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Der Nachfolger von "Tomorrow's Chemistry Today": Die besten Nachwuchschemiker Europas stellen Ihnen Trends und Perspektiven in der organischen Chemie vor. Zu den Themen gehören unter anderem die Organokatalyse und neue Synthesestrategien.
Table des matières
PrefacePART I: Innovative Processes in Organic ChemistryN-HYDROXY DERIVATIVES: KEY ORGANOCATALYSTS FOR THE SELECTIVE FREE RADICAL AEROBIC OXIDATION OF ORGANIC COMPOUNDSIntroductionGeneral Reactivity of N-Hydroxy DerivativesAerobic Oxidation Catalyzed by N-Hydroxy AminesAerobic Oxidation Catalyzed by N-Hydroxy AmidesAerobic Oxidation Catalyzed by N-Hydroxy ImidesConclusionsGOLD-CATALYZED INTRA- AND INTERMOLECULAR CYCLOADDITIONS OF PUSH-PULL DIENYNESIntroductionGold-Catalyzed Enyne CycloisomerizationsGold-Catalyzed Intermolecular CycloadditionsConclusions and Future PerspectivesN-HETEROCYCLIC CARBENES IN COPPER-CATALYZED REACTIONSIntroductionPreparation of NHC-Containing Copper ComplexesMain Applications of [(NHC)Cu] Complexes in CatalysisCopper Hydride-Mediated Reactions[3+2] Cycloadditions of Azides and AlkynesConcluding RemarksSUPPORTED ORGANOCATALYSTS AS A POWERFUL TOOL IN ORGANIC SYNTHESISIntroductionL-Proline and its Derivatives on Ionic Liquid-Modified Silica GelsPolystyrene-Supported Proline as a Versatile and Recyclable OrganocatalystProlinamide-Supported Polystyrenes as Highly Stereoselective and Recyclable Organocalysts for the Aldol ReactionOutlook and Future PerspectivesTHE COMPLEX-INDUCED PROXIMITY EFFECT IN ORGANOLITHIUM CHEMISTRY AND ITS IMPORTANCE IN THE LITHIATION OF TERTIARY AMINESIntroductionState of the ArtLatest DevelopmentsConclusions and OutlookPART II: Predictive Tools in Organic Chemical ReactionsDOUBLE HYDROGEN BONDING IN ASYMMETRIC ORGANOCATALYSIS: A MECHANISTIC PERSPECTIVEIntroductionDiols and Amidoalcohols(Thio)ureasPhosphoric AcidsOther CatalystsConclusions and OutlookDYNAMIC COVALENT CAPTURE: A SENSITIVE TOOL FOR DETECTING MOLECULAR INTERACTIONSIntroductionHydrogen Bond-Driven Self-Assembly in Aqueous SolutionMeasuring Stability and Order in Biological StructuresDrug DiscoveryCatalyst DiscoveryThe Analysis of Complex Chemical SystemsPerspectivePART III: Chemical Reactions, Sustainable Processes, and EnvironmentFURFURAL AND FURFURAL-BASED INDUSTRIAL CHEMICALSCarbohydrates for LifeFurfural-Evolution over Nearly Two CenturiesApplications of FurfuralMechanistic Considerations on the Conversion of Pentosans into FurfuralProduction of FurfuralConclusion and Future PerspectiveMULTIPLE BOND-FORMING TRANSFORMATIONS: THE KEY CONCEPT TOWARD ECO-COMPATIBLE SYNTHETIC ORGANIC CHEMISTRYThe Science of SynthesisMultiple Bond-Forming Transformations (MBFTs)An Account of Our Recent ContributionsConclusionMODELING OF INDIRECT PHOTOTRANSFORMATION REACTIONS IN SURFACE WATERSIntroductionIndirect Photolysis Processes in Surface WatersModeling the Photochemistry of Surface WatersConclusions and PerspectivesPART IV: Organic Synthesis and MaterialsBOTTOM-UP APPROACHES TO NANOGRAPHENES THROUGH ORGANIC SYNTHESISIntroductionAlternant Polyarenes with 10 Fused Benzene RingsAlternant Polyarenes with 11 Fused Benzene RingsAlternant Polyarenes with 12 Fused Benzene RingsAlternant Polyarenes with 13 Fused Benzene RingsAlternant Polyarenes with 14 Fused Benzene RingsAlternant Polyarenes with More Than 150 Fused Benzene RingsConclusions and OutlookDIFFERENTIATED LIGANDS FOR THE SEQUENTIAL CONSTRUCTION OF CRYSTALLINE HETEROMETALLIC ASSEMBLIESIntroductionDithiolate LigandsDipyrrin LigandsConclusion and OutlookWATER-SOLUBLE PERYLENE DYESHistory and Functionalization of Perylene DyesDerivatization of Perylene DyesProperties and Applications of Perylene DyesAdvantages and Applications of Water-Soluble Perylene DerivativesSymmetric Water-Soluble PDIsUnsymmetric PDIsChiral Water-Soluble PDIsConclusion and Outlook
A propos de l'auteur
Bruno Pignataro, born in Bologna in 1972, is Professor of Physical Chemistry at the University of Palermo. He received his degree in chemistry in 1995 from the University of Catania and his PhD in materials science five years later. He has helped establish a wide network of international collaborations and organized more than 10 meetings at national and international level, including coordinating the Young Chemists Group of the Italian Chemical Society and chairing the 1st and the 2nd European Young Chemist Award. He is a referee for several leading chemistry and materials journals, has more than 50 scientific publications and about 80 conference communications to his name, along with several invited lectures.Professor Pignataros research interests focus on the related fields of the physical chemistry of molecular surfaces and soft nanotechnologies. He is in the Editorial Board of Chemistry Central Journal, is editing by La Chimica e l'Industria a new heading on Critical Reviews and also acted as the editor of the recently published book, 'Tommorow's Chemistry Today: Concepts in Nanoscience, Organic Materials and Environmental Chemistry', which provides an overview of rising young scientists in the fields of organic materials, nanotechnology and environmental chemistry.
Résumé
Der Nachfolger von "Tomorrow's Chemistry Today": Die besten Nachwuchschemiker Europas stellen Ihnen Trends und Perspektiven in der organischen Chemie vor. Zu den Themen gehören unter anderem die Organokatalyse und neue Synthesestrategien.