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Focusing on preparation and applications in synthesis and catalysis, this book finally closes a gap in the literature by summarizing this hot topic for the first time.
As such, it gathers in one volume the key features of metal vinylidene and allenylidene complexes as well as reactive species and covers applications in metathesis, polymerization, molecular materials, carbon rich compounds and fine chemical production. The emphasis here is on the selective transformations of alkynes and enynes plus simple and complex molecules containing a triple C-C bond.
The result is a must-have ready reference for organic, catalytic, complex, theoretical and polymer chemists, as well as those working with/on organometallics.
Table des matières
Preparation and stoichiometric reactivity of metal vinylidenes complexes
Preparation and stoichiometric reactivity of metal allenylidenes complexes
Preparation and reactivity of higher metal cumulenes
Theoretical aspects of metal vinylidene and allenylidene complexes
Anti-Markovnikov additions of nucleophiles to triple bonds (C-O, C-N, C-P, C-C dimerization)
Group 6 metal vinylidenes in catalysis (Cr, Mo, W)
Ruthenium vinylidenes and allenylidenes in catalysis for carbocyclization
Allenylidene binuclear complexes in catalysis
Ruthenium vinylidenes and allenylidenes precursors for olefin metathesis
Metal vinylidenes in metathesis polymerization
A propos de l'auteur
Pierre H. Dixneuf is professor of chemistry at the University of Rennes, now Emeritus Professor. He has created a team on Organometallic Chemistry and Catalysis, and in 2000 he founded the Research Institute of Chemistry of Rennes. He has developed successively several processes in ruthenium catalysed reactions: transformations of alkynes, incorporation of CO2, ruthenium-vinylidenes and allenylidenes in catalysis, catalytic synthesis of heterocycles, alkene metahesis catalysts and applications, C-H bond activation including in water. He has designed many new ruthenium catalysts especially involving metal-carbene bond. He has published more than 380 papers, edited 2 books and owns 5 patents. He is a member of Institute Universitaire de France (IUF) since 2000.
Résumé
Focusing on preparation and applications in synthesis and catalysis, this book finally closes a gap in the literature by summarizing this hot topic for the first time.
As such, it gathers in one volume the key features of metal vinylidene and allenylidene complexes as well as reactive species and covers applications in metathesis, polymerization, molecular materials, carbon rich compounds and fine chemical production. The emphasis here is on the selective transformations of alkynes and enynes plus simple and complex molecules containing a triple C-C bond.
The result is a must-have ready reference for organic, catalytic, complex, theoretical and polymer chemists, as well as those working with/on organometallics.
Commentaire
"This book provides a timely compilation of information related to an emerging area of modern synthetic organic chemistry and should prove to be an excellent source for students, faculty, and chemists in the chemical industry interested in applying or learning about this aspect of alkyne chemistry." ( Journal of the American Chemical Society , November 2008)
