X-Rays and Materials

Klappentext This book presents reviews of various aspects of radiation/matter interactions, be these instrumental developments, the application of the study of the interaction of X-rays and materials to a particular scientific field, or specific methodological approaches.The overall aim of the book is to provide reference summaries for a range of specific subject areas within a pedagogical framework. Each chapter is written by an author who is well known within their field and who has delivered an invited lecture on their subject area as part of the "RX2009 - X-rays and Materials" colloquium that took place in December 2009 at Orsay in France.The book consists of five chapters on the subject of X-ray diffraction, scattering and absorption.Chapter 1 gives a detailed presentation of the capabilities and potential of beam lines dedicated to condensed matter studies at the SOLEIL synchrotron radiation source.Chapter 2 focuses on the study of nanoparticles using small-angle X-ray scattering.Chapter 3 discusses the quantitative studies of this scattering signal used to analyze these characteristics in detail.Chapter 4 discusses relaxor materials, which are ceramics with a particularly complex microstructure. Chapter 5 discusses an approach enabling the in situ analysis of these phase transitions and their associated microstructural changes. Zusammenfassung This book presents reviews of various aspects of radiation/matter interactions, be these instrumental developments, the application of the study of the interaction of X-rays and materials to a particular scientific field, or specific methodological approaches.The overall aim of the book is to provide reference summaries for a range of specific subject areas within a pedagogical framework. Each chapter is written by an author who is well known within their field and who has delivered an invited lecture on their subject area as part of the "RX2009 - X-rays and Materials" colloquium that took place in December 2009 at Orsay in France.The book consists of five chapters on the subject of X-ray diffraction, scattering and absorption.Chapter 1 gives a detailed presentation of the capabilities and potential of beam lines dedicated to condensed matter studies at the SOLEIL synchrotron radiation source.Chapter 2 focuses on the study of nanoparticles using small-angle X-ray scattering.Chapter 3 discusses the quantitative studies of this scattering signal used to analyze these characteristics in detail.Chapter 4 discusses relaxor materials, which are ceramics with a particularly complex microstructure. Chapter 5 discusses an approach enabling the in situ analysis of these phase transitions and their associated microstructural changes. Inhaltsverzeichnis Preface xi Chapter 1. Synchrotron Radiation: Instrumentation in Condensed Matter 1 Jean-Paul ITIE! Francois BAUDELET! Valerie BRIOIS! Eric ELKAIM! Amor NADJI and Dominique THIAUDIERE 1.1. Introduction 1 1.2. Light sources in the storage ring 2 1.3. Emittance and brilliance of a source 6 1.4. X-ray diffraction with synchrotron radiation 8 1.5. X-ray absorption spectroscopy usingsynchrotron radiation 13 1.6. SAMBA: the X-ray absorption spectroscopy beam line of SOLEIL for 4--40 keV 20 1.7. The DIFFABS beam line 27 1.8. CRISTAL beam line 34 1.9. The SOLEIL ODE line for dispersive EXAFS 38 1.10. Conclusion 43 1.11. Bibliography 44 Chapter 2. Nanoparticle Characterization using Central X-ray Diffraction 49 Olivier SPALLA 2.1. Introduction 49 2.2. Definition of scattered intensity 50 2.3. Invariance principle 52 2.4. Behavior for large q: the Porod regime 55 2.5. Particle-based systems 59 2.6. An absolute scale for measuring particle numbers 75 2.7. Conclusion 78 2.8. Bibliography 79 Chapter 3. X-ray Diffraction for Structural Studies of Carbon Nanotubes and their Insertion Compounds 81 Julien CAMBEDOUZOU and Pascale LAUNOIS 3.1. Introduction 81 3.2. Single-walled ca...

Table des matières

Preface xi

Chapter 1. Synchrotron Radiation: Instrumentation inCondensed Matter 1
Jean-Paul ITIE, François BAUDELET, Valérie BRIOIS, EricELKAÏM, Amor NADJI and Dominique THIAUDIÈRE

1.1. Introduction 1

1.2. Light sources in the storage ring 2

1.3. Emittance and brilliance of a source 6

1.4. X-ray diffraction with synchrotron radiation 8

1.5. X-ray absorption spectroscopy usingsynchrotron radiation13

1.6. SAMBA: the X-ray absorption spectroscopy beam line ofSOLEIL for 4-40 keV 20

1.7. The DIFFABS beam line 27

1.8. CRISTAL beam line 34

1.9. The SOLEIL ODE line for dispersive EXAFS 38

1.10. Conclusion 43

1.11. Bibliography 44

Chapter 2. Nanoparticle Characterization using Central X-rayDiffraction 49
Olivier SPALLA

2.1. Introduction 49

2.2. Definition of scattered intensity 50

2.3. Invariance principle 52

2.4. Behavior for large q: the Porod regime 55

2.5. Particle-based systems 59

2.6. An absolute scale for measuring particle numbers 75

2.7. Conclusion 78

2.8. Bibliography 79

Chapter 3. X-ray Diffraction for Structural Studies of CarbonNanotubes and their Insertion Compounds 81
Julien CAMBEDOUZOU and Pascale LAUNOIS

3.1. Introduction 81

3.2. Single-walled carbon nanotubes 85

3.3. Multi-walled carbon nanotubes 96

3.4. Hybrid nanotubes 102

3.5. Textured powder samples 110

3.6. Conclusion 121

3.7. Bibliography 122

Chapter 4. Dielectric Relaxation and Morphotropic Phases inNanomaterials 129
Jean-Michel KIAT

4.1. Introduction 129

4.2. Dielectric relaxation and morphotropic region: definitionand mechanism 130

4.3. Relaxation, morphotropic region and size reduction 163

4.4. Conclusion 174

4.5. Acknowledgements 175

4.6. Bibliography 175

Chapter 5. Evolution of Solid-state Microstructures inPolycrystalline Materials: Application of High-energy X-rayDiffraction to Kinetic and Phase Evolution Studies 181
Elisabeth AEBY-GAUTIER, Guillaume GEANDIER, Moukrane DEHMAS, FabienBRUNESEAUX, Adeline BENETEAU, Patrick WEISBECKER, BenoîtAPPOLAIRE and Sabine DENIS

5.1. Introduction 181

5.2. Experimental methods 183

5.3. Results 195

5.4. Conclusion 213

5.5. Acknowledgements 214

5.6. Bibliography 214

List of Authors 221

Index 223

A propos de l'auteur

Philippe Goudeau is director of research at CNRS and head of the thin film mechanical properties team at the PHYMAT laboratory in Poitiers in France. His research concerns the study of size effects on the mechanical properties of thin films by X-ray diffraction in laboratory and on synchrotron sources.
René Guinebretière is Professor at ENSCI in Limoges, France. He teaches X-ray diffraction and materials physics. He carries out research into the development and characterization of oxide nanomaterials by X-ray diffraction at the SPCTS laboratory associated with CNRS.

Résumé

This book reviews various aspects of radiation/matter interactions, including instrumental developments, the application of the interaction of X-rays and materials to a particular scientific field, and specific methodological approaches. The book draws on lectures from the RX2009 X-rays and Materials colloquium, delivered by experts in the field.

Détails du produit

• Auteurs: P Goudeau, P. Goudeau, Philippe Goudeau, Rene Guinebretiere
• Collaboration: Philipp Goudeau (Editeur), Philippe Goudeau (Editeur), GUINEBRETIERE (Editeur), Guinebretiere (Editeur), Rene Guinebretiere (Editeur)
• Edition: Wiley, John and Sons Ltd
• Langues: Anglais
• Format d'édition: Livre Relié
• Sortie: 27.03.2012
• EAN: 9781848213425
• ISBN: 978-1-84821-342-5
• Thèmes: ISTE; ISTE
• Catégories: Sciences naturelles, médecine, informatique, technique > Technique > Général, dictionnaires; Materialwissenschaften, Materials science, Spezialthemen Materialwissenschaften, Materials Science Special Topics