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This first handbook on this hot subject presents current processing methods suitable for the fabrication of micro and nanostructured surfaces made out of polymeric materials. It covers the steps and polymeric materials involved, as well as the resulting structures, and is rounded off by a section on the manifold fields of application, such as disposable biomedical devices, tissue engineering and implant fabrication, biofouling, biomimetic surfaces and photonic structures.
As a result, chemists, material scientists and physicists gain a critical understanding of this topic at an early stage of its development.
Inhaltsverzeichnis
PrefacePART I: MoldingMATERIALS AND PROCESSES IN UV-ASSISTED NANOIMPRINT LITHOGRAPHYIntroductionUV-Assisted Nanoimprint LithographyImprinting MaterialsMold Fabrication and Anti-Sticking StrategiesConclusionROLL-TO-ROLL NANOIMPRINT LITHOGRAPHY AND DYNAMIC NANO-INSCRIPTIONIntroductionRoll-to-Roll Nanoimprint LithographyDynamic Nano-InscriptionSummarySOLVENT-ASSISTED MOLDINGThe Principle of Solvent-Assisted MoldingSolvent-Assisted Molding with a Good SolventSolvent-Assisted Molding with a Poor SolventOther TechniquesApplications of Solvent-Assisted MoldingConclusionsSOFT LITHOGRAPHY AND VARIANTSIntroductionKey Features of Soft LithographyMicrocontact Printing of Self-Assembled MonolayersSoft Molding TechniquesSummaryPART II: Writing and PrintingTRANSFER PRINTING PROCESSESIntroductionTechniquesKey Issues in Transfer Printing MethodsAdvantages and DisadvantagesApplicationsDIRECT-WRITE ASSEMBLY OF 3D POLYMERIC STRUCTURESIntroductionPolyelectrolyte InksSilk Fibroin InksHydrogel InksOpportunities and ChallengesPART III: Laser ScanningTHREE-DIMENSIONAL MICROFABRICATION BY TWO-PHOTON POLYMERIZATIONIntroductionFundamentalsMaterialsExperimental SetupResolutionMicrostructures: Properties and CharacterizationApplicationsLimitations and Future DirectionsLASER MICROMACHINING OF POLYMERSIntroductionPrinciples of Beam-Matter Interaction in Ablation ProcessesLaser Ablation of PolymersLaser-Induced RougheningGenerative Laser ProcessesConclusionPART IV: Self OrganizationCOLLODAL POLYMER PATTERNINGIntroductionEmulsion PolymerizationForces and Mechanisms in Polymer DispersionPolymer Patterns from Colloidal SuspensionsSummary and OutlookDIRECTED SELF-ASSEMBLY OF BLOCK COPOLYMER FILMSIntroductionEnergetics of the Basic Directed Assembly SystemExamples of Directed AssemblyConclusionSURFACE INSTABILITY AND PATTERN FORMATION IN THIN POLYMER FILMSIntroductionOrigin of Surface InstabilityPolymer Thin Film DewettingDewetting on Patterned SubstratesInstability due to Externally Imposed FieldsConclusionPART V: ApplicationsCELLS ON PATTERNSIntroductionPhysicochemical Properties of the Substrate Read by CellsConclusionsPOLYMER PATTERNS AND SCAFFOLDS FOR BIOMEDICAL APPLICATIONS AND TISSUE ENGINEERINGIntroductionCell Response to 2D PatternsCells onto 3D Objects and ScaffoldsConcluding RemarksNANO- AND MICRO-STRUCTURED POLYMER SURFACES FOR THE CONTROL OF MARINE BIOFOULINGIntroductionReplica Molding in PDMS and Other PolymersStretched Topographies in PDMSStructured Surfaces by Self-AssemblyNanocompositesNanostructured Polymer Surfaces by Vapor Deposition MethodsConclusionsBIOINSPIRED PATTERNED ADHESIVESIntroductionVertical StructuresTilted StructuresCoated StructuresHierarchical Structures3D StructuresSwitchable AdhesionOutlookPATTERNED MATERIALS AND SURFACES FOR OPTICAL APPLICATIONSIntroductionOptical Micro- and Nanostructures for ApplicationsConclusion
Über den Autor / die Autorin
Prof. Eduard Arzt: currently Scientific Director of Leibniz Institute for New Materials, Saarbruecken, Germany, and Professor for New Materials, Saarland University (2007 to present). Ph.D. in physics, University of Vienna, Austria (1980). Post-doctoral position, University of Cambridge, UK (1981/82). Group leader, Max-Planck-Institut für Metallforschung, Stuttgart (1982-89). Visiting Professor, Stanford University (1989/90). Director, Max-Planck-Institut für Metallforschung and Professor of Metal Physics, University of Stuttgart, Germany (1990 to 2007). Visiting Professor and R.S. Williams Lecturer at the Massachusetts Institute of Technology (1996). Recipient of e.g. the Acta Metallurgica Outstanding Paper Award, Max-Planck-Research Award, and Gottfried Wilhelm Leibniz Prize. Corresponding member, Austrian Academy of Sciences, and Member, German Academy Leopoldina.
Dr. Aránzazu del Campo is heading the department "Functional Surfaces" at the Leibniz Institute for New Materials, Saarbrücken. After getting her PhD degree in Chemistry in 2000, she joined the Max-Planck-Institut für Polymerforschung in Mainz (Germany) as Marie Curie Fellow. In 2003 she moved as Senior Researcher to the Universitá degli Studi di Urbino (Italy), and from 2004 to 2007 she lead an independent research group at the Max-Planck-Institute in Stuttgart (Germany). Her current research work focuses on the development of patterned and responsive polymeric surfaces and materials for controlling and switching adhesion-related phenomena. She has been awarded the Young-Scientist Award 2007 from the Federation of European Material Scientists.
Zusammenfassung
New micro and nanopatterning technologies have been developed in the last years as less costly and more flexible alternatives to phtolithograpic processing. These technologies have not only impacted on recent developments in microelectronics, but also in emerging fields such as disposable biosensors, scaffolds for tissue engineering, non-biofouling coatings, high adherence devices, or photonic structures for the visible spectrum. This handbook presents the current processing methods suitable for the fabrication of micro- and nanostructured surfaces made out of polymeric materials. It covers the steps and materials involved, the resulting structures, and is rounded off by a part on applications. As a result, chemists, material scientists, and physicists gain a critical understanding of this topic at an early stage of its development.