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Klappentext The current volume continues the tradition of the Organic Syntheses series, providing carefully checked and edited experimental procedures that describe important synthetic methods, transformations, reagents, and synthetic building blocks or intermediates with demonstrated utility in organic synthesis. These significant and interesting procedures should prove worthwhile to many synthetic chemists working in increasingly diverse areas. A trusted guide for professionals in organic and medicinal chemistry in academia, government, and industries, including pharmaceuticals, fine chemicals, agrochemicals, and biotechnological products. Inhaltsverzeichnis Copper and Secondary Amine-Catalyzed Pyridine Synthesis from O -Acetyl Oximes and ¿,ß-Unsaturated Aldehydes 1 Wei Wen Tan, Bin Wu, Ye Wei, and Naohiko Yoshikai An Au/Zn-catalyzed Synthesis of N-Protected Indole via Annulation of N-Arylhydroxamic Acid and Alkyne 15 Xinpeng Cheng, Yanzhao Wang, and Liming Zha Preparation of Fac-Tris(2-Phenylpyridinato) Iridium(III) 29 Kip A. Teegardin and Jimmie D. Weaver Preparation of Cyclopent-2-enone Derivatives via the Aza-Piancatelli Rearrangement 46 Meghan F. Nichol, Luis Limon, and Javier Read de Alaniz Catalytic, Metal-Free Oxidation of Primary Amines to Nitriles 60 Kyle M. Lambert, Sherif A. Eldirany, James M. Bobbitt, and William F. Bailey Copper-Catalyzed Enantioselective Hydroamination of Alkenes 80 Richard Y. Liu and Stephen L. Buchwald Preparation of 6H-Benzo[c]chromen-6-one 97 Yang Wang, Yi Shi, and Vladimir Gevorgya Synthesis of N-Acyl Pyridinium-N-Aminides and Their Conversion to 4-Aminooxazoles via a Gold-Catalyzed Formal (3+2)-Dipolar Cycloaddition 112 Matthew P. Ball-Jones and Paul W. Davies Preparation of Solid Organozinc Pivalates and Their Reaction in Pd-Catalyzed Cross-Couplings 127 Mario Ellwart, Yi-Hung Chen, Carl Phillip Tüllmann, Vladimir Malakhov, and Paul Knochel Enantioselective Synthesis of (S)-Ethyl 2-((tert-butoxycarbonyl)(( tert butyldimethylsilyl) oxy)amino)-4 oxobutanoate 142 Thibault J. Harmand, Claudia E. Murar, Hikaru Takano, and Jeffrey W. Bode Preparation of (S)-N-Boc-5-oxaproline 157 Claudia E. Murar, Thibault J. Harmand, Hikaru Takano, and Jeffrey W. Bode Syntheses of Substituted 2-Cyano-benzothiazoles 177 Hendryk Würfel and Dörthe Jakobi Preparation of N -(1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ylidene) nitramide 192 Emerson Teixeira da Silva, Adriana Marques Moraes, Adriele da Silva Araújo, and Marcus Vinícius Nora de Souza Preparation of Alkyl Boronic Esters Using Radical-Polar Crossover Reactions of Vinylboron Ate Complexes 205 Marvin Kischkewitz and Armido Studer Preparation of (pin)B-B(dan) 218 Hiroto Yoshida, Yuya Murashige, and Itaru Osaka Discussion Addendum for: Preparation of a Carbazole-Based Macrocycle Via Precipitation-Driven Alkyne Metathesis 231 Christopher C. Pattillo, Morgan M. Cencer, and Jeffrey S. Moore Hydrodecyanation by a Sodium Hydride-Iodide Composite 240 Guo Hao Chan, Derek Yiren Ong, and Shunsuke Chiba Indole-Catalyzed Bromolactonization: Preparation of Bromolactone in Lipophilic Media 256 Zhihai Ke, Tao Chen, and Ying-Yeung Yeung Discussion Addendum for: Stereoselective Synthesis of 3-Arylacrylates by Copper-Catalyzed Syn Hydroarylation [( E )-Methyl 3-phenyloct-2-enoate] 267 Yoshihiko Yamamoto Modified McFadyen-Stevens Reaction for a Versatile Synthesis of Aromatic Aldehydes 276 Yuri Iwai and Jun Shimokawa Discussion Addendum for: Facile Syntheses of Aminocyclopropanes: N,N -Dibenzyl- N -(2-ethenylcyclopropyl)amine [(Benzenemethanamine, N -(2-ethenylc...
