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Polymer modifications represent a valuable synthetic approach to unique polymer compositions, structure, and properties not readily available by the direct polymerization of monomers. Modified polymeric products already exist in the commercial world (modified celluloses, for example) so the approach is not new. However, it is an interesting and chaU~nging opportunity to develop new materials for a variety of specialty applications using the "chemistry on polymers" approach. This book contains papers presented at the symposium on Polymer Modification held at the National American Chemical Society Meeting in Orlando, Florida, August, 1996. The chemistry presented is broad ranging, and includes grafting and chemical oxidation reactions, and many other chemical modifications. Hopefully, the book will be both a resource and an inspiration for the reader to develop new opportunities for his or her particular applications. CONTENTS SURF ACE MODIFICATIONS The Preparation of Methyl Methacrylate/Methacrylic Anhydride Copolymers from PMMA and Dialkyl Amines via Reaction Extrusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Michael P. Hallden-Abberton Grafting of Hindered Amine Groups on EPDM and Polyoctenamer via Photo- Hydroperoxidation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 J. Lacoste, S. Chmela, J. Pellet, and J. F. Pilichowski Reactive Gases as Reagents for Polymer Films Chemical Modifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 J. F. Pilichowski, S. Commereuc, 1. Lukac, G. Teissedre, and J. Lacoste The Synthesis of Hydrophobe-Modified Hydroxyethyl Cellulose Polymers Using Phase Transfer Catalysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 Emmett M. Partain The Synthesis and Characterization of Polyesters Derived from L-Lactide and Variably-Sized Poly(Caprolactone) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 Michael R. Lostocco and Samuel J.
Sommario
Surface Modifications.- The Preparation of Methyl Methacrylate/Methacrylic Anhydride Copolymers from PMMA and Dialkyl Amines via Reaction Extrusion.- Grafting of Hindered Amine Groups on EPDM and Polyoctenamer via Photo-Hydroperoxidation.- Reactive Gases as Reagents for Polymer Films Chemical Modifications.- The Synthesis of Hydrophobe-Modified Hydroxyethyl Cellulose Polymers Using Phase Transfer Catalysis.- The Synthesis and Characterization of Polyesters Derived from L-Lactide and Variably-Sized Poly(Caprolactone).- Reactions with Vinyl Polymers.- The Functionalization of Polyolefins by Using Reactive Intermediates.- Chemical Modification of Acrylamide Polymers in Aqueous Solution.- Synthesis and Characterization of Poly(Magnesium Acrylate) and Poly(Zirconyl Acrylate) towards the Formation of Magnesium Partially Stabilized Zirconia Ceramics.- Preparation of Functionalized Polymers by Reactions of Poly(Vinylbenzyl Chloride).- Graft Copolymerization of Vinyl Monomers onto Polymers Containing Styrene.- Chemical Cross-Linking by Glutaraldehyde between Amino Groups: Its Mechanism and Effects.- Poly(Chlorotrifluoroethylene) Substituted Reactions.- Inorganic-Containing and Shaped Polymers.- Synthesis and Structural Characterization of Inorganic Tin Ionomers.- Computer Modeling of Poly(Acrylic Acid) and Its Salts.- Synthesis and Structural Characterization of Titanocene-Containing Polyethers Based on Reaction with Ethylene Oxide-Containing Diols, Including Poly(Ethylene Glycol).- Synthesis of Novel Silanol Polymers and Copolymers by a Selective Oxidation of Si-H Bond from Corresponding Precursor Polymers.- Synthesis and Ion-Coupling Reactions of Telechelic Poly(Dimethylsiloxane) Having Cyclic Onium Salt Groups.- An Empirical and Modeling Study of Boron Speciation inSolution with a Reactive Dendrimeric Polymer.- Author Index.
Riassunto
Proceedings of an ACS-PMSE Division Symposium held in Orlando, Florida, August 21-25, 1996
