Ulteriori informazioni
The Handbook of Reagents for Organic Synthesis: Catalytic Oxidation Reagents is part of the Handbook for Reagents for Organic Synthesis series, making use of the leading reagent database e-EROS. It provides concise and informative articles written by experts in the area and provides comprehensive referencing to the original literature. As is the standard format for EROS, each article also contains an overview of the synthesis and physical properties of the catalysts, conditions for its storage, and purification methods.
The Handbook compiles essential reagents in this area, starting with an introductory section discussing the main classes of oxidation catalysts, followed by an alphabetical list of reagents, with an attempt to keep families of catalysts organized by related chemistry for ease of use. The Handbook concludes with a list of contributors and a detailed index.
The Handbook of Reagents for Organic Synthesis: Catalytic Oxidation Reagents if of interest for everyone engaged in the area of sustainable chemistry, fuel alternatives research for the generation of energy, and synthetic chemists working in pharmaceutical industries and medicinal chemistry.
Key features:
* Builds on the success of the previously published Handbooks of Reagents for Organic Synthesis
* Oxidations are the most frequently used steps in organic synthesis
* Catalysts for oxidation reactions are the key for green or sustainable chemistry
* Oxidation, the addition of oxygen to biomolecules, is key for the metabolism of humans and animals
* Oxidations of carbohydrates from simple organic compounds are the key for new renewable energies
Sommario
Preface xi
Introduction xiii
Terminal Oxidants Finder xv
Oxidation Catalyst Finder xix
Recent Review Articles and Monographs xxv
Short Note on InChIs and InChIKeys xxvii
4-Acetamido-2,2,6,6-tetramethyl-1-piperidinyloxyl 1
4-Acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium Tetrafluoroborate 2
Bathocuproine 15
Bathophenanthroline 17
Benzenecarboperoxoic acid, 1, 1-dimethylethyl Ester 20
1,2-Benziodoxol-3(1H)-one, 1-Hydroxy, 1-Oxide, IBX 32
1,2-Benziodoxol-3(1H)-one, 1-Hydroxy, 1-Oxide, stabilized (stabilized IBX) 44 1,4-Benzoquinone 49
cis-4-Benzyloxy-alpha,alpha-bis-(3,5-dimethylphenyl)-Lprolinol (2S,4R)- 52
2,2_-Bipyrrolidines, (2S,2_S) and (2R,2_R) 54
2-[Bis-[3,5-bis(trifluoromethyl)Phenyl] [(trimethylsilyl)oxy]Methyl]Pyrrolidine 57
2,2-Bis[2-[4(S)-tert-butyl-1,3-oxazolinyl]]propane 59
Bis[[(1R,1__R)-3,3__-[(1R,2R)-1,2-cyclohexanediylbis [(nitrilo-kappaN)methylidyne]]bis[2_-phenyl[1,1_-
binaphthalen]-2-olato-kappaO]](2-)]di-mu-oxodi-titanium and Bis[[(1S,1__S)-3,3__-[(1S,2S)-1,2- cyclohexanediylbis[(nitrilo-kappaN)methylidyne]]bis [2_-phenyl[1,1_-binaphthalen]-2-olato-kappaO]](2-)]di- mu-oxodi-titanium 66
Bis(2,2-dimethylpropanoato - kappa-O)phenyl-iodine 69
Bis(1-methyl-1-phenylethyl) Peroxide 77
1,2-Bis(phenylsulfinyl)ethane 79
N,N_-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene Palladium(I) Allyl Chloride 82
Bis(trimethylsilyl) Peroxide 87
Bromamine-T 91
N-tert-Butyl-N-chlorocyanamide 94
tert-Butyl Hydroperoxide 96
tert-Butyl Hypochlorite 126
tert-Butyl Peracetate 132
Calcium Hypochlorite 137
Chloramine-T 142
Chlorobenzene 150
Chloro[N,N_-ethylenebis(salicylideneaminato)] manganese 152
Chromium(VI) Oxide 157
Chromyl Acetate 163
Cobalt, [5,10,15,20-tetraphenyl-21H,23Hporphinato( 2.)-kappaN 21,kappaN 22,kappaN 23,kappaN 24]- 167
Cumyl Hydroperoxide 171
N,N_-(1R,2R)-1,2-Cyclohexanediylbis- [N-hydroxy-alpha-phenybenzeneacetamide] 179
1,5-Diaza-cis-decalin 183
N,N-Dibromobenzenesulfonamide and N,N-Dibromo-p-toluenesulfonamide 188
Di-mu-chlorobis(1,5-cyclooctadiene)diiridium(I) 195
Di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,-3,4,5- pentamethyl-2,4-cyclopentadien-1-yl]diiridium 202
(R)-2,10-Dichloro-5H-dinaphtho[2,1-g: 1,2-i][1,5]dioxacycloundecin-3,6,9(7h)-trione 210
Dichloro(ethoxy)oxovanadium(V) 213
1,1_-Difluoro-2,2_-bipyridinium Bis-(tetrafluoroborate) 217
1,2:4,5-Di-O-isopropylidene-ß-d-erythro-hexo-2,3- diulo-2,6-pyranose 221
Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I) 224
Dimethyldioxirane 228
(S,S)-2,2_-(Dimethylmethylene)bis(4-tert-butyl-2- oxazoline) and (R,R)-2,2_-(Dimethylmethylene)bis- (4-tert-butyl- 2-oxazoline) 234
Dispiro[2H-pyran-2,4_-[4H-5,6,8b]triazaacenaphthylene- 7_(5_H),2__-[2H]pyran], 1_,2_,2_a,3,3_,3__,4,4__,5,5__,
6,6__,8_,8_a-tetradecahydro-1_,2_-dimethoxy-6,6__- dimethyl-, monohydrochloride, (1_S,2R,2_S,2__R, 2_aS,6S,6__S,8_aS)- 257
N-fluoro-N-(phenylsulfonyl)-benzenesulfonamide 259
N-Fluoropyridinium Tetrafluoroborate 270
N-Fluoropyridinium Triflate 272
1-Fluoro-2,4,6-trimethylpyridinium Tetrafluoroborate 274
1-Fluoro-2,4,6-trimethylpyridinium Trifluoromethanesulfonate 278
Hydrogen Peroxide 281
Hydrogen Peroxide-Urea 295
N-Hydroxyphthalimide 307
Iodine 317
2-Iodobenzenesulfonic Acid 332
Iodosylbenzene 338
Iridium, [N-[(
Info autore
Professor Philip L. Fuchs, Department of Chemistry, Purdue UniversityPhilip Fuchs began his career at Purdue in 1973. Since that time, he has graduated an extended family of 55 Ph.D.s. His awards and honors include an Eli Lilly young faculty fellowship (1975), an Alfred P. Sloan fellowship (1977), a Pioneer in Laboratory Robotics award (1986), a Martin teaching award (1991), and being voted by the students as one of Top 10 Teachers in School of Science at Purdue (1991, 1993, 1995, 1996).
Fuchs has consulted for Pfizer, and Eli Lilly, served on the editorial board of The Journal of Organic Chemistry, and is currently an executive editor for the
Electronic Encyclopedia of Organic Reagents (e-EROS), an online dynamic encyclopedia published by John Wiley & Sons.
Riassunto
Reduction and oxidation processes are at the heart of almost all synthetic procedures and organic chemists are keen to have a huge portfolio of slick and modern catalytic reagents performing oxidations or reductions. This new volume is part of the Handbook for Reagents for Organic Synthesis series, making use of the leading reagent database e-EROS.
