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Informationen zum Autor Nina Berova is a Research Professor in the Department of Chemistry at Columbia University. She has been a coeditor of the journal Chirality (Wiley) since 1998. Prasad L. Polavarapu is currently a Professor of Chemistry at Vanderbilt University. Koji Nakanishi is one of the world's leading natural products chemists and was editor of the journal, The Chemical Record (Wiley). He retired from Columbia University in 2007, but continues to conduct research. Robert W. Woody is an Emeritus Professor at Colorado State University. Klappentext The definitive guide to chiroptical spectroscopyProviding an introduction to the methods of chiroptical spectroscopy, this two-volume set presents comprehensive coverage of the most important and up-to-date methods of dealing with chiral molecules, which can discriminate between left and right circularly polarized light. Addressing basic principles, instrumentation, and applications in the natural sciences, Comprehensive Chiroptical Spectroscopy is the only book of its kind to provide cutting-edge, in-depth coverage of recent developments and frontier topics in the field, looking at the most important applications of chiroptical spectroscopy to problems in organic and inorganic chemistry, biochemistry, and structural biology.Topics covered in the second volume include:* Aromatic chromophores* Exciton chirality method* Inorganic systems* Chiral natural products* Peptides, proteins, nucleic acids, and carbohydrates* Drug and natural product binding to nucleic acids* And much moreWith each chapter written by one or more leading authorities in the field, Comprehensive Chiroptical Spectroscopy presents the ideal tools needed to determine chiral molecular structures and associated molecular properties, making it a must-have for both students and researchers. Zusammenfassung This book introduces the important methods of chiroptical spectroscopy in general, and circular dichroism (CD) in particular, which are increasingly important in chemistry, biochemistry, and structural biology. It functions well as an undergraduate and graduate text, and as a research reference, with or without the companion volume in this set. Inhaltsverzeichnis Comprehensive Chiroptical Spectroscopy, Volume 2 PREFACE xi CONTRIBUTORS xiii PART I A HISTORICAL OVERVIEW 1 1 THE FIRST DECADES AFTER THE DISCOVERY OF CD AND ORD BY AIME COTTON IN 1895 3 Peter Laur PART II ORGANIC STEREOCHEMISTRY 37 2 SOME INHERENTLY CHIRAL CHROMOPHORES-EMPIRICAL RULES AND QUANTUM CHEMICAL CALCULATIONS 39 Marcin Kwit, Pawel Skowronek, Jacek Gawronski, Jadwiga Frelek, Magdalena Woznica, and Aleksandra Butkiewicz 3 ELECTRONIC CD OF BENZENE AND OTHER AROMATIC CHROMOPHORES FOR DETERMINATION OF ABSOLUTE CONFIGURATION 73 Tibor Kurtan, Sandor Antus, and Gennaro Pescitelli 4 ELECTRONIC CD EXCITON CHIRALITY METHOD: PRINCIPLES AND APPLICATIONS 115 Nobuyuki Harada, Koji Nakanishi, and Nina Berova 5 CD SPECTRA OF CHIRAL EXTENDED p -ELECTRON COMPOUNDS: THEORETICAL DETERMINATION OF THE ABSOLUTE STEREOCHEMISTRY AND EXPERIMENTAL VERIFICATION 167 Nobuyuki Harada and Shunsuke Kuwahara 6 ASSIGNMENT OF THE ABSOLUTE CONFIGURATIONS OF NATURAL PRODUCTS BY MEANS OF SOLID-STATE ELECTRONIC CIRCULAR DICHROISM AND QUANTUM MECHANICAL CALCULATIONS 217 Gennaro Pescitelli, Tibor Kurtan, and Karsten Krohn 7 DYNAMIC STEREOCHEMISTRY AND CHIROPTICAL SPECTROSCOPY OF METALLO-ORGANIC COMPOUNDS 251 James W. Canary and Zhaohua Dai 8 CIRCULAR DICHROISM OF DYNAMIC SYSTEMS: SWITCHING MOLECULAR AND SUPRAMOLECULAR CHIRALITY 289 Angela Mammana, Gregory T. Carroll, and Ben L. Feringa 9 ELECTRONIC CIRCULAR DICHROISM OF SUPRAMOLECULAR SYSTEMS 317 Ch...
