Catalysis - From Principles to Applications

Allen, die sich im Studium mit Katalyse beschäftigen, sei dieser Band dringend empfohlen. Er behandelt alle wesentlichen theoretischen Prinzipien; Einsatzmöglichkeiten von Katalysatoren in der Industrie werden anhand interessanter Fallstudien verdeutlicht.

List of contents

PREFACEPART I: Basic ConceptsCATALYSIS IN PERSPECTIVE: HISTORIC REVIEWHistory of Catalysis ScienceThe Development of Catalytic Processes: History and FutureFundamental Catalysis in PracticeCatalyst SelectionReactor ChoiceProcess ChoiceKINETICS OF HETEROGENEOUS CATALYTIC REACTIONSPhysical chemical principlesThe Lock and Key Model, the Role of Adsorption EntropyEquivalence of Electrocatalysis and ChemocatalysisMicrokinetics; the Rate-Determining StepElementary Rate Constant Expressions for Surface ReactionsThe Pressure GapThe Materials GapCoupling of Catalytic Reaction and Inorganic Solid ChemistryIn situ Generation of Organo-CatalystThe Compensation EffectKINETICS IN HOMOGENEOUS CATALYSISPrinciples of a Catalyst and Kinetic DescriptionCatalyst ActivityCatalyst Activation and DeactivationCATALYTIC REACTION ENGINEERING PRINCIPLESPrefaceFormal Kinetics of Catalytic ReactionsMass and Heat Transfer EffectsHomogenous Catalysis in Biphasic Fluid/Fluid SystemsPART II: The Chemistry of Catalytic ReactivityHETEROGENEOUS CATALYSISGeneral IntroductionTransition Metal CatalysisSolid Acids and BasesReducible OxidesHOMOGENEOUS CATALYSISGeneral FeaturesBIOCATALYSISIntroductionExamplesSummary/ConclusionsELECTROCATALYSISIntroductionTheoryApplication to the Oxygen Reduction Reaction (ORR) on Pt(111)SummaryHETEROGENEOUS PHOTOCATALYSISIntroductionApplications of PhotocatalysisCase StudiesConcluding RemarksPART III: Industrial Catalytic ConversionsCARBONYLATION REACTIONSGeneral AspectsHydroformylationOther Carbonylations of Olefins and AlkynesCarbonylations of Alcohols and Aryl HalidesBIOCATALYTIC PROCESSESIntroductionExamplesCase Study: Synthesis of Lipitor Building BlocksConclusionsPOLYMERIZATIONIntroductionPolyolefins in BriefOlefin Polymerization CatalystsOlefin Polymerization Process TechnologyThe Latest BreakthroughsAMMONIA SYNTHESISAmmonia PlantSynthesisSteam ReformingConclusionsFISCHER-TROPSCH SYNTHESIS IN A MODERN PERSPECTIVEIntroductionStoichiometry and Thermodynamic AspectsProcesses and Product CompositionCatalysts, GeneralReaction FundamentalsConcluding RemarksZEOLITE CATALYSISIntroductionThe Hydrocracking Reaction; Acid CatalysisLewis Acid - Lewis Base Catalysis; Hydrocarbon ActivationSelective Oxidation; Redox CatalysisFramework-Substituted Redox IonsCATALYTIC SELECTIVE OXIDATION - FUNDAMENTALS, CONSOLIDATED TECHNOLOGIES, AND DIRECTIONS FOR INNOVATIONCatalytic Selective Oxidation: Main FeaturesCatalytic Selective Oxidation: What Makes the Development of an Industrial Process More Challenging (and Troublesome) than Other ReactionsCatalytic Selective Oxidation: the Forefront in the Continuous Development of More-Sustainable Industrial TechnologiesThe Main Issue in Catalytic Oxidation: the Control of SelectivityDream Reactions in Catalytic Selective Oxidation: a Few Examples (Some Sustainable, Some Not Sustainable)A New Golden Age for Catalytic Selective Oxidation?Conclusions: Several Opportunities for More Sustainable Oxidation ProcessesHIGH-TEMPERATURE CATALYSIS: ROLE OF HETEROGENEOUS, HOMOGENEOUS, AND RADICAL CHEMISTRYIntroductionFundamentalsApplicationsHydrogen Production from Logistic Fuels by High-Temperature CatalysisHigh-Temperature Catalysis in Solid Oxide Fuel CellsHYDRODESULFURIZATIONIntroductionHydrodesulfurizationThe C-X Bond-Breaking MechanismStructure of the Sulfidic CatalystHydrodenitrogenationDetermination of Surface SitesPART IV: Catalyst Synthesis and MaterialsMOLECULARLY DEFINED SYSTEMS IN HETEROGENEOUS CATALYSISIntroductionSingle Sites: On the Border between Homogeneous and Heterogeneous CatalysisConclusion and PerspectivesPREPARATION OF SUPPORTED CATALYSTSIntroductionSupport Surface ChemistryIon AdsorptionImpregnation and DryingDeposition PrecipitationThermal TreatmentPOROUS MATERIALS AS CATALYSTS AND CATALYST SUPPORTSGeneral CharacteristicsSol-gel and Fumed SilicaAlumina and Other OxidesCarbon MaterialsZeolitesOrdered Mesoporous MaterialsMetal-Organic FrameworksShapingDEVELOPMENT OF CATALYTIC MATERIALSIntroductionFundamental AspectsMicro-Kinetics and Solid-State Properties as a Knowledge Source in Catalyst DevelopmentCombinatorial Approaches and High-Throughput Technologies in the Development of Solid CatalystsPART V: Characterization MethodsIN-SITU TECHNIQUES FOR HOMOGENEOUS CATALYSISIntroductionIn-situ Techniques for Homogeneous CatalysisGas Consumption and Gas FormationNMR SpectroscopyIR-SpectroscopyUV/Vis SpectroscopySummaryIN-SITU CHARACTERIZATION OF HETEROGENEOUS CATALYSTSIntroductionSome History, Recent Developments, and ApplicationsIn situ Characterization of a Reactor Loaded with a Catalytic SolidIn situ Characterization at a Single Catalyst Particle LevelConcluding RemarksADSORPTION METHODS FOR CHARACTERIZATION OF POROUS MATERIALSIntroductionPhysical AdsorptionClassification of Porous MaterialsAdsorption IsothermsThe Application of Adsorption MethodsTheoretical Description of AdsorptionCharacterization of Microporous MaterialsCharacterization of Mesoporous MaterialsMercury PorosimetryXenon PorosimetryA CRITICAL REVIEW OF SOME "CLASSICAL" GUIDELINES FOR CATALYST TESTINGIntroductionEncouraging EffectivenessEnsuring EfficiencyConcluding RemarksAPPENDIX A: THREE-PHASE TRICKLE-BED REACTORSPART VI: Catalytic Reactor EngineeringCATALYTIC REACTOR ENGINEERINGIntroductionTypes of Catalytic ReactorsIdeal Reactor Modeling/Heat ManagementResidence Time DistributionMicro Reaction Engineering

About the author

Matthias Beller obtained his PhD at the University of Göttingen, Germany and completed a postdoctoral fellowship at the Massachusetts Institute of Technology in Cambridge, USA. Since 1998, he has been head of the Leibniz Institute for Organic Catalysis at University of Rostock. He is a member of the board of Dechema's Catalysis Section, the German Catalysis Competence Network ("ConNeCat") as well as the Innovationsagentur Mecklenburg-Vorpommern. He is also a member of the Association for Technical Sciences of the Union of German Academies of Sciences and Humanities.

Albert Renken obtained his academic degrees at the Technical University of Hanover, Germany. Professor Renken has been affiliated with ETH Lausanne, Switzerland since 1977. He is author of over 350 scientific publications in journals and books and of numerous patents. From 1992 to 2000, Albert Renken was science councillor of the Swiss National Science Foundation (SNF), and from 1996 to 2000 he served as chairman of the European Federation of Chemical Reaction Engineering Working Party.

Rutger Anthony van Santen gained his doctorate from the University of Leiden, Netherlands. He became Professor of Catalysis at the Eindhoven University of Technology, where he was also promoted to scientific director. In 1991 he became director of the Netherlands Institute of Research in Catalysis, and in 2005 he was made Royal Netherlands Academy of Science and Arts Professor. He is a member of the Royal Dutch Academy of Arts and Sciences, Dutch Academy of Engineering and is a Knight in the order of the Dutch Lion. Professor van Santen is the author or editor of 13 books, over 600 research papers and 22 patents, and has been awarded several national and international awards and visiting professorships.

Summary

Allen, die sich im Studium mit Katalyse beschäftigen, sei dieser Band dringend empfohlen. Er behandelt alle wesentlichen theoretischen Prinzipien; Einsatzmöglichkeiten von Katalysatoren in der Industrie werden anhand interessanter Fallstudien verdeutlicht.

Report

"Overall, this is a useful book for process chemists with the reservation that modern carbon-carbon bond forming catalytic reactions (Buchwald-Hartwig, Suzuki-Miyaura, Heck etc) are not covered. The emphasis is definitely towards heterogenous catalysis." ( Organic Process Research & Development Journal , 1 November 2012)

Product details

• Authors: Matthias Beller, Albert Renken, Rutger A. van Santen
• Assisted by: Matthias Beller (Editor), Albert Renken (Editor), Rutger A. van Santen (Editor), Rutger A. VanSanten (Editor)
• Publisher: Wiley-VCH
• Languages: English
• Product format: Hardback
• Released: 01.08.2012
• EAN: 9783527323494
• ISBN: 978-3-527-32349-4
• No. of pages: 642
• Weight: 1360 g
• Illustrations: 262 SW-Abb., 26 Farbabb., 39 Tabellen
• Subject: Natural sciences, medicine, IT, technology > Chemistry > Organic chemistry