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Informationen zum Autor Rosemary A. Marusak is former chair of the Chemistry Department and cochair of the Biochemistry/Molecular Biology Program at Kenyon College. She is completing a degree in veterinary medicine at Michigan State and is a?research associate in the CVM-MSU Equine Foot Laboratory where she conducts cell biology and molecular biology research investigating diseases of the equine foot. Kate Doan! a former assistant professor of chemistry at Kenyon College! is currently pursuing master's degrees in science education and mathematics education at the University of Minnesota. Scott D. Cummings! PhD! is an Associate Professor of Chemistry at Kenyon College. Klappentext An integrative, investigative approach to coordination chemistryThis book offers a series of investigative inorganic laboratory exercises approached through systematic coordination chemistry. After an introduction that provides an overview of complex coordination concepts, Integrated Approach to Coordination Chemistry: An Inorganic Laboratory Guide leads readers on a progressive, graduated exploration of experimentation in the inorganic field.*Core chapters cover: inorganic synthesis and quantitative analysis; molecular structure; substitution kinetics; and electron transfer reactions*Advanced topics emphasize major applications of coordination complexes that have emerged over the past several decades: metals in medicine, the environment, molecular biology, and organic synthesis*Each chapter features a project overview, at least five related experiments, and detailed references for further study*The book conveys the historical development of coordination chemistry via experiment setsThis guide includes experiments appropriate for college students at all levels, including graduate students. While they get a concise review of coordination chemistry, students also grasp the fundamentals of investigative techniques. An excellent lab manual, this is also ideal for students in bioinorganic chemistry and instrumental analysis. A complementary Instructor's Manual helps instructors plan, develop, and customize courses. Zusammenfassung Integrated Approach to Coordination Chemistry: An Inorganic Laboratory Guide offers a comprehensive and systematic investigative overview of coordination chemistry presented within the context of the historical development of the field and through experimental discovery in the laboratory. Inhaltsverzeichnis Acknowledgments.1. Experimental Inorganic Chemistry: A History of Dazzling Color!2. Levels 1-2. Werner's Notion--Creating the Field: Synthesis and Analysis of Cobalt Ammine Coordination Compounds.3. Levels 3 and 4. Molecular Geometry and Stability: Solid and Solution Phase Analysis of N,N'-disalicylaldehyde-1,3-propanediimine nickel(II).4. Levels 3-4. Reactivity I: Substitution Reactions--The Reaction of Aquapentacyanoferrate(II) Ion [Fe(CN)5(H2O)]³- with Amino Acids.5. Levels 4 and 5. Electron Transfer Reactions--Structure, Properties and Reactivity of Tris(bidentate chelate) cobalt(II/III) Complexes.6. Levels 4 and 5. Metals in Medicine: Synthesis and Biological Reactivity of the Platinum Anticancer Drug, cis-Platin and its Isomer, trans-Platin.7. Levels 4 and 5. Metals in the Environment--Cd^2+ Sequestration by Phytochelatins and Bioremediation.8. Level 5. Metals in Molecular Biology--Synthesis, Photophysical and Chiral Properties of Tris(1,10-Phenanthroline)Chromium(III): Metal Complex DNA Interactions and Reactivity.9. Level 5. Oxidation of a Natural Product by a Vanadium Catalyst: Synthesis and Catalytic Activity of Vanadyl-bis (2,4-pentanedione), VO(acac)2.Appendix 1. Introduction to Pulsed NMR Spectroscopy of Metal Complexes.Appendix 2. Introduction to Cyclic Voltammetry.Appendix 3. States and Term Symbols for Polyelectronic Systems.Appendix 4. Setting up an Maintaining CHO Cell Culture.Appendix 5. Setting Up and Maintaining Yea...
