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A unique book that incorporates of research on radical Brook rearrangements.
List of contents
Chapter 1 Introduction
Chapter 2 Generation of a-siloxy radicals with a-silyl alcohol through radical Brook rearrangement
2.1 Metal free reactions
2.2 Metal-catalyzed reactions
2.3 Photocatalyzed reactions
2.4 Electrophotocatalyzed reactions
2.4 Other reactions
Chapter 3 Generation of a-siloxy radicals with acylsilane through radical Brook rearrangement
3.1 Radical initiation
3.2 Metal-catalyzed reactions
3.3 Photocatalyzed reactions
3.4 Other reactions
Chapter 4 Generation of a-siloxy silyl radicals with (TMS)3SiOH through radical Brook rearrangement
4.1 Metallaphotoredox reactions
4.2 Photoredox reactions
4.3 Metallaphotoredox reaction with (TMS)3SiNHAd
Chapter 5 Generation of siloxycarbenes for nucleophilic addition reaction
5.1 Aldehydes or ketones as electrophiles
5.2 Other electrophilic reagents
Chapter 6 Generation of siloxycarbenes for insertion reaction
6.1 Carbene insertion reactions into O?H bonds
6.2 Carbene insertion reactions into N?H bonds
6.3 Carbene insertion reactions into other X?H bonds
6.4 Carbene insertion reactions into B?C bonds
6.5 Carbene insertion reactions into C?H bonds
Chapter 7 Generation of siloxycarbenes for cycloaddition reaction
7.1 [2+1] cycloaddition with alkynes
7.2 [2+1] cycloaddition with alkenes
7.3 [4+1] cycloaddition with dienes and a,ß-unsaturated ketones
7.4 [2+2] Cycloaddition Reaction of a-Ketoacylsilanes with Imines
7.5 other cyclization reaction
Chapter 8 Generation of siloxycarbenes for metal siloxycarbene reaction
8.1 Metal siloxycarbene reactions
8.2 Aminooxycarbene Reactions
Chapter 9 Generation of silenes through radical Brook rearrangement
9.1 Insertion reactions
9.2 [2+2] Cycloaddition reactions
9.3 [4+2] Cycloaddition reactions
9.4 Other reactions
Chapter 10 Reference
About the author
Xiao Shen is Professor at the Institute for Advanced Studies, Engineering Research Centre of Organosilicon Compounds & Materials, Ministry of Education, Wuhan University, China. In 2018, he was selected into the "Youth Thousand Talents Program" of China, and in 2021, he was selected into the "Thousand Talents Program" of Jiangxi Province. In 2022, he was appointed as the Principal Investigator of a Young Scientist Project of the National Key R&D Program. He is a member of Youth Editorial Board of Chinese Chemical Letters and a member of Early Career Advisory Board of Organic Chemistry Frontiers. In 2023, he won the "Thieme Chemistry Journals Award".
Yunxiao Zhang is a post-doctoral fellow of The Institute for Advanced Studies of Wuhan University, China. In June 2021, he received his Ph.D from Wuhan University under the supervision of Prof. Xiao Shen. His research interests focus on photocatalysis and organofluorine/organosilicon chemistry.
Gang Zhou is a post-doctoral fellow of The Institute for Advanced Studies of Wuhan University, China. He studied organic chemistry at Wuhan University and obtained his Ph.D under the supervision of Prof. Xiao Shen in June 2023. His research interests focus on photocatalysis and organosilicon chemistry.
Summary
A unique book that incorporates of research on radical Brook rearrangements.
