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Informationen zum Autor Allan F.M. Barton Klappentext Develops the concept of solubility parameters from empirical! thermodynamic! and molecular points of view. This book demonstrates their application to liquid! gas! solid! and polymer systems. Zusammenfassung Develops the concept of solubility parameters from empirical, thermodynamic, and molecular points of view. This book demonstrates their application to liquid, gas, solid, and polymer systems. Inhaltsverzeichnis INTRODUCTION. THERMODYNAMICS. Cohesive Energy. Cohesive Pressure and the Hildebrand Parameter. Thermodynamic Equation of State. Empirical Equations of State. Units and Conversion Factors. Mixtures. Phase Separation. MOLECULAR INTERACTIONS. Electrical Properties. Dipole-Dipole Interactions. Dipole-Induced Dipole Interactions. Induced Dipole-Induced Dipole Interactions. Spectroscopic Studies. Positron Annihilation. REGULAR SOLUTIONS AND THE HILDEBRAND PARAMETER. Geometric Mean Approximation. Hildebrand-Scatchard Equation. Limitations of the Hildebrand-Scatchard Equation. Mixed Liquids and Multicomponent Systems. Solvent Spectra. Wilson Equation. EXPANDED COHESION PARAMETERS. Dispersion. Orientation. Induction. Lewis Acid-Base. Hydrogen-Bonding Association. Combination of Component Cohesion Parameters. Empirical Corrections for Geometric Mean Deviations. Polar-Nonpolar Cohesion Parameters. Hansen Parameters. Fractional Three-Component Cohesion Parameters. Other Two- and Three-Component Cohesion Parameters. Other Multi-Component Cohesion Parameters. Modified Separation of Cohesive Energy Density. Liquid Metals. CALCULATED COHESION PARAMETERS. Group Molar Vaporization Enthalpy. Group Molar Cohesive Energy. Molar Additive Functions. Group Molar Attraction Constants. Group Molar Volumes. Group Cohesion Parameters. Homomorphs and Dispersion Cohesion Parameters. Hansen Parameter Group Contributions. Participating and Nonparticipating Groups. Comparison of Methods. LIQUID PHASES. Vaporization Enthalpy. Vapor Pressure. Boiling Point. Corresponding States. Internal Pressure and Cohesive Pressure. Liquid-Liquid Miscibility. Binary Solvents. Activity Coefficients in Liquid-Liquid Systems. Complexes. Solvent-Aided Separation. Liquid Extraction. Acidity-Basicity Linear Energy Scales. SOLVENT SCALES. Hydrogen Bonding. Electrostatic Parameters and Empirical Relationships. Single Component Donor-Acceptor Parameters. Hybrid Cohesion Parameter Solvent Scales. Practical Solvent Scales. E...
