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Informationen zum Autor Thomas Rauchfuss received his undergraduate degree from the University of Puget Sound (1971) and his Ph.D. from Washington State University (1976). He has studied overseas at the following institutions: the Australian National University, University of Auckland, University of Strasbourg, and the Technical University of Karlsruhe. He is interested in all aspects of the synthesis and reactivity of inorganic, organometallic, and main-group compounds and materials.?He is a winner of the prestigious ACS Award in Inorganic Chemistry, and is Fellow of both the American Chemical Society and the Japan Society for the Promotion of Science.?Among others, Dr. Rauchfuss has held the Guggenheim Fellowship as well as the Alfred P. Sloan Fellowship,and has written numerous papers and book chapters. Klappentext The Inorganic Syntheses series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds.* Includes complete, up-to-date procedures involving important inorganic substances* Contains subject, contributor, and formula indexes Zusammenfassung The Inorganic Syntheses series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds.* Includes complete, up-to-date procedures involving important inorganic substances* Contains subject, contributor, and formula indexes Inhaltsverzeichnis Preface. Contributors. Dedication. Notice to Contributors and Checkers. Toxic Substances and Laboratory Hazards. Chapter One COMPLEXES OF BULKY ß-DIKETIMINATE LIGANDS. 1. Introduction. 2. ß-Diketiminate Precursors HLMe,Me3 and TlLMe,Me3 (LMe,Me3 = 2,4-Bis-(Mesitylimido)Pentyl). 3. ß-Diketiminate Precursors LMe,iPr2H, [LMe,iPr2Li]x, and [LtBu,iPr2K]x (LMe,iPr2 = 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl; LtBu,iPr2 = 2,2,6,6- Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl). 4. ß-Diketiminate Precursors LtBu,iPr2H and LtBu,iPr2Li(THF) (LtBu,iPr2=2,2,6,6-Tetramethyl-3,5- Bis-(2,6-Diisopropylphenylimido)Heptyl). 5. Scandium Trichloride Tris(Tetrahydrofuran) and ß-Diketiminate-Supported Scandium Chloride Complexes. 6. ß-Diketiminate-Supported Titanium and Vanadium Dichloride Complexes. 7. ß-Diketiminate-Supported Vanadium and Chromium Chloride Complexes. 8. ß-Diketiminate-Supported Manganese and Zinc Complexes. 9. Iron 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2FeCl). 10. Iron 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl Chloride (LtBu,iPr2FeCl). 11. Cobalt 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido) Heptyl Chloride (LtBu,iPr2CoCl). 12. ß-Diketiminate-Supported Nickel(II) and Nickel(I) Complexes of LMe,Me3 (LMe,Me3 = 2,4-Bis-(Mesitylimido)Pentyl). 13. Nickel 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride Dimer, [LMe,iPr2Ni(µ-Cl)]2. 14. Bis[Copper 2,4-Bis-(2,4,6-Trimethylphenylimido)Pentyl] Toluene, (LMe,Me3Cu)2(µ-n2:n2-C7H8). 15. Copper 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2CuCl). Chapter Two BORON CLUSTER COMPOUNDS. 16. Salts of Dodecamethylcarba- closo -Dodecaborate(-) Anion, CB11Me12, and the Radical Dodecamethylcarba- closo -Dodecaboranyl, CB11Me12. 17. Cesium Dodecahydroxy- closo -Dodecaborate, Cs2[B12(OH)12]. Chapter Three COORDINATION COMPOUNDS. 18. Pentaaquanitrosylchromium Sulfate. 19. The Tetradentate Bispidine Ligand Dimethyl-(3,7-Dimethyl-9-oxo-2,4-bis(2-pyridyl)-3,7-Diazabicyclo[3.3.1]nonane)-1, 5-dicarboxylate and Its Copper(ll) Complex. 20. Tris(2-Picolinyl)Methane and Its Copper(I) Complex. Chapter Four CARBENE LIGANDS AND COMPLEXES. 21. 1,3-Dialkyl-Imidazole-2-Ylidenes. 22. A Chelating Rhodium N<...
