Read more
Informationen zum Autor Marcel Gielen , Professor Emeritus, Free University of Brussels, Belgium. Member of the Editorial Board on the journal, Applied Organometallic Chemistry . Rudolph Willem , Free University of Brussels, Belgium. Member of the Editorial Board on the journal, Applied Organometallic Chemistry . Bernd Wrackmeyer , Universitat Bayreuth, Germany. Member of the Editorial Board on the journal, Magnetic Resonance in Chemistry . Klappentext This series offers leading contributions by well-known chemists reviewing the state of the art of this wide research area. Physical organometallic chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry.This volume focuses on several important topics on fluxionality in organometallic and coordination chemistry, reviewed by experts in each of the respective fields. It is intended to provide both authoritative concepts and stimulating ideas in order to tackle dynamics from different angles, aiming at an interdisciplinary approach. The fascinating fluxionality of metal-ligand interactions has been in the centre of interest ever since modern coordination and organometallic chemistry started, and has expanded towards bioinorganic chemistry, catalysis and materials sciences.* Provides information on some of the most relevant physical methods for studying dynamic processes* Presents numerous examples of dynamic behavior, demonstrating the efficiency of the respective method and stimulating further applications* Connects main group, transition metal and solid state chemistry in the question for dynamics Zusammenfassung This series offers leading contributions by well-known chemists reviewing the state of the art of this wide research area. Physical organometallic chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry.This volume focuses on several important topics on fluxionality in organometallic and coordination chemistry, reviewed by experts in each of the respective fields. It is intended to provide both authoritative concepts and stimulating ideas in order to tackle dynamics from different angles, aiming at an interdisciplinary approach. The fascinating fluxionality of metal-ligand interactions has been in the centre of interest ever since modern coordination and organometallic chemistry started, and has expanded towards bioinorganic chemistry, catalysis and materials sciences.* Provides information on some of the most relevant physical methods for studying dynamic processes* Presents numerous examples of dynamic behavior, demonstrating the efficiency of the respective method and stimulating further applications* Connects main group, transition metal and solid state chemistry in the question for dynamics Inhaltsverzeichnis Contributors. Series Preface. Preface. 1. Polyhedral Dynamics and the Jahn-Teller Effect ( R. Bruce King ). 1. Introduction. 2. Polyhedron Topology. 3. Polyhedral Isomerizations: Microscopic Models. 3.1 Diamond-Square-Diamond Processes. 3.2 Gale Diagrams. 3.3 Generation of Metallaborane Structures by Diamond-Square-Diamond Transformations in Deltahedra. 4. Polyhedral Isomerizations: Macroscopic Models. 4.1 Topological Representations of Polyhedral Isomerizations. 4.2 Topological Representations of Jahn-Teller Distortions. 5. Acknowledgement. 6. References. 2. NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes ( I. D. Gridnev and O. L. Tok ). 1. Introduction. 2. Discovery Activation Parameters of [1,3]-B Shifts. 3. Fluxional Linear Polyunsaturated Allylboranes. 3.1 2,4-Pentadienyl(di- n -propyl)borane. 3.2 2,4,6-Heptatrienyl(di- n ...
