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Informationen zum Autor G. T. Hefter and R. P. T. Tomkins are the authors of The Experimental Determination of Solubilities, published by Wiley. Klappentext * Guidelines are provided on the reliability of various methods, as well as information for selecting the appropriate technique.* Unique coverage of the whole range of solubility measurements.* Very useful for investigators interested in embarking upon solubility measurements. Zusammenfassung Dealing with solubility measurements, this book discusses procedures for measurement of various types of solubility data, as assessed by experienced researchers in various areas. Inhaltsverzeichnis List of Contributors xi Series Preface xv Preface xvii Acknowledgements xxi List of Symbols xxiii Quantities, Units and Conversions 1 John W. Lorimer 1. Quantities and Units Used to Describe Solubility 2 2. Quantities and Units Used to Describe Solubilities of Gases 6 3. References 14 1 Fundamentals of Solubility 17 Chapter 1.1 Thermodynamics of Solubility 19 John W. Lorimer and Roger Cohen-Adad 1. Introduction 19 2. Basic Definitions in Thermodynamics of Solubility 19 3. Thermodynamics of Solubility 22 4. Solubility of Gases in Liquids 26 5. Solubility of Liquids in Liquids 41 6. Solubility of Solids in Liquids 50 7. Concluding Remarks 62 8. References 62 Appendix A: Some Useful Thermodynamic Concepts and Relations 70 Appendix B: Numerical and Statistical Procedures in Constructing Fitting Equations 74 Chapter 1.2 Kinetics and Mechanisms of Crystal Growth and Dissolution 77 Jørgen Christoffersen and Margaret R. Christoffersen 1. Introduction 77 2. Fundamental Concepts 77 3. Mechanisms and Rate Expressions for Dissolution and Growth 81 4. Comparison of Dissolution and Precipitation Kinetics 93 5. Kinetics of Approach to Equilibrium 93 6. Summary of Rate-determining Mechanisms 95 7. Acknowledgement 95 8. References 96 2 Gases 99 Chapter 2.1 Solubility of Gases in Liquids 101 H. Lawrence Clever and Rubin Battino 1. Introduction 101 2. Quantities Used as a Measure of Gas Solubility 102 3. The Solution Components 107 4. Degassing The Solvent 108 5. Experimental Methods 110 6. Related Experiments that Complement Gas Solubility Data 130 7. Treatment of Data 132 8. Standards 137 9. Summary and Recommendations 144 10. References 145 Chapter 2.2 Solubility of Gases in Polymers 151 Y uri Y ampolski and Russell Paterson 1. Introduction 151 2. Manometric Methods 152 3. Gravimetric Methods 156 4. Inverse Gas Chromatography 160 5. Miscellaneous 165 6. Conclusions 167 7. References 168 Chapter 2.3 Solubility of Gases in Molten Salts and Molten Metals 173 Reginald P.T. Tomkins 1. Solubility of Gases in Molten Salts 173 2. Solubility of Gases in Molten Metals 203 3. References 215 Chapter 2.4 Solubility of Gases in Solid Metals 219 Y Sakamoto and F. A. Lewis 1. Sieverts Method 220 2. Equilibrate.Quench.Analyze Method 222 3. Gravimetric Method 224 4. Changes of Lattice Parameters and Electrical Resistivity Due to Dissolved Hydrogen in Metals 225 5. Determination of Changes of Hydrogen Solubilities from Measurements of Electrode Potential Under Conditions of Controlled Electolyte Stirring 228 6. References 232 3 Liquids 235 Chapter 3 Liquid-Liquid Solubilities 237 Glenn T. Hefter 1. In...
