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Unter Zirkulardichroismus (CD) versteht man die spezifisch unterschiedliche Absorption von links- und rechtszirkular polarisiertem Licht durch bestimmte Moleküle. CD-Effekte lassen sich in Abhängigkeit von der Wellenlänge messen und spektroskopisch auswerten; sie geben beispielsweise Auskunft über die Konformation organischer Verbindungen. Dieses Buch richtet sich an den organischen Chemiker, der mit den Grundprinzipien der Stereochemie vertraut ist, und erläutert die Anwendung der CD-Spektroskopie zur Konformationsanalyse ausführlich und verständlich. (06/00)
List of contents
Cyclohexane and Cyclohexanone.
Optical Activity.
The Octant Rule.
Conformational Analysis of Substituted Cyclohexanones.
Other Cycloalkanones.
Saturated Bicyclic Ketones.
Saturated Polycyclic Ketones.
Isotopically Perturbed Ketones.
Diketones.
Unsaturated and Cyclopropyl Ketones.
Dienes.
Biaryls and Helicenes.
Exciton Coupling and Exciton Chirality.
Indexes.
About the author
DAVID A. LIGHTNER, PhD, is R. C. Fuson Professor of Chemistry at the University of Nevada, Reno.
JEROME E. GURST, PhD, is Professor of Chemistry at the University of West Florida, Pensacola.
Summary
A unique guide to variable temperature CD spectroscopy and its application in organic chemistry This timely, original, thought-provoking work looks at organic stereochemistry from the perspective of circular dichroism (CD), using variable temperature CD spectroscopy to determine the conformation or absolute configuration of chiral molecules.
Additional text
"I feel that this book will form a valuable source to all those interested in stereochemistry and conformational analysis of small molecules. This book will very useful..." (Talanta, Vol 53, 2001)
"It is a must for libraries and for all research groups engaged in experimental or theoretical work in this area." (Angewandte Chemie International Edition, Vol. 40 No. 9)
"...strongly recommended for research libraries serving organic and pharmaceutical chemists and...to some individuals working in those areas." (Journal of the American Chemical Society, Vol. 124, No. 12, 2002)
Report
"I feel that this book will form a valuable source to all those interested in stereochemistry and conformational analysis of small molecules. This book will very useful..." (Talanta, Vol 53, 2001)
"It is a must for libraries and for all research groups engaged in experimental or theoretical work in this area." (Angewandte Chemie International Edition, Vol. 40 No. 9)
"...strongly recommended for research libraries serving organic and pharmaceutical chemists and...to some individuals working in those areas." (Journal of the American Chemical Society, Vol. 124, No. 12, 2002)
