Organic Corrosion Inhibitors - Synthesis, Characterization, Mechanism, and Applications

Provides comprehensive coverage of organic corrosion inhibitors used in modern industrial platforms, including current developments in the design of promising classes of organic corrosion inhibitors
 
Corrosion is the cause of significant economic and safety-related problems that span across industries and applications, including production and processing operations, transportation and public utilities infrastructure, and oil and gas exploration. The use of organic corrosion inhibitors is a simple and cost-effective method for protecting processes, machinery, and materials while remaining environmentally acceptable. Organic Corrosion Inhibitors: Synthesis, Characterization, Mechanism, and Applications provides up-to-date coverage of all aspects of organic corrosion inhibitors, including their fundamental characteristics, synthesis, characterization, inhibition mechanism, and industrial applications.
 
Divided into five sections, the text first covers the basics of corrosion and prevention, experimental and computational testing, and the differences between organic and inorganic corrosion inhibitors. The next section describes various heterocyclic and non-heterocyclic corrosion inhibitors, followed by discussion of the corrosion inhibition characteristics of carbohydrates, amino acids, and other organic green corrosion inhibitors. The final two sections examine the corrosion inhibition properties of carbon nanotubes and graphene oxide, and review the application of natural and synthetic polymers as corrosion inhibitors. Featuring contributions by leading researchers and scientists from academia and industry, this authoritative volume:
* Discusses the latest developments and issues in the area of corrosion inhibition, including manufacturing challenges and new industrial applications
* Explores the development and implementation of environmentally-friendly alternatives to traditional toxic corrosion inhibitors
* Covers both established and emerging classes of corrosion inhibitors as well as future research directions
* Describes the anticorrosive mechanisms and effects of acyclic, cyclic, natural, and synthetic corrosion inhibitors
 
Offering an interdisciplinary approach to the subject, Organic Corrosion Inhibitors: Synthesis, Characterization, Mechanism, and Applications is essential reading for chemists, chemical engineers, researchers, industry professionals, and advanced students working in fields such as corrosion inhibitors, corrosion engineering, materials science, and applied chemistry.

List of contents

Preface xv
 
About the Editors xvii
 
List of Contributors xix
 
Part I Basics of Corrosion and Prevention 1
 
1 An Overview of Corrosion 3
Marziya Rizvi
 
1 Introduction 3
 
1.1 Basics about Corrosion 3
 
1.2 Economic and Social Aspect of Corrosion 4
 
1.3 The Corrosion Mechanism 5
 
1.3.1 Anodic Reaction 6
 
1.3.2 Cathodic Reactions 7
 
1.4 Classification of Corrosion 8
 
1.4.1 Uniform Corrosion 8
 
1.4.2 Pitting Corrosion 9
 
1.4.3 Crevice Corrosion 9
 
1.4.4 Galvanic Corrosion 9
 
1.4.5 Intergranular Corrosion 10
 
1.4.6 Stress-Corrosion Cracking (SCC) 10
 
1.4.7 Filiform Corrosion 10
 
1.4.8 Erosion Corrosion 10
 
1.4.9 Fretting Corrosion 11
 
1.4.10 Exfoliation 11
 
1.4.11 Dealloying 11
 
1.4.12 Corrosion Fatigue 11
 
1.5 Common Methods of Corrosion Control 11
 
1.5.1 Materials Selection and Design 12
 
1.5.2 Coatings 12
 
1.5.3 Cathodic Protection (CP) 12
 
1.5.4 Anodic Protection 13
 
1.5.5 Corrosion Inhibitors 13
 
1.6 Adsorption Type Corrosion Inhibitors 13
 
1.6.1 Anodic Inhibitors 14
 
1.6.2 Cathodic Inhibitors 14
 
1.6.3 Mixed Inhibitors 14
 
1.6.4 Green Corrosion Inhibitors 15
 
References 15
 
2 Methods of Corrosion Monitoring 19
Sheerin Masroor
 
2.1 Introduction 19
 
2.2 Methods and Discussion 21
 
2.2.1 Corrosion Monitoring Techniques 21
 
2.3 Conclusion 33
 
References 33
 
3 Computational Methods of Corrosion Monitoring 39
Hassane Lgaz, Abdelkarim Chaouiki, Mustafa R. Al-Hadeethi, Rachid Salghi, and Han-Seung Lee
 
3.1 Introduction 39
 
3.2 Quantum Chemical (QC) Calculations-Based DFT Method 40
 
3.2.1 Theoretical Framework 40
 
3.2.2 Theoretical Application of DFT in Corrosion Inhibition Studies: Design and Chemical Reactivity Prediction of Inhibitors 42
 
3.2.2.1 HOMO and LUMO Electron Densities 43
 
3.2.2.2 HOMO and LUMO Energies 43
 
3.2.2.3 Electronegativity (s), Chemical Potential (mu), Hardness (eta), and Softness (sigma) Indices 43
 
3.2.2.4 Electron-Donating Power (omega.) and Electron-Accepting Power (omega+) 44
 
3.2.2.5 The Fraction of Electrons Transferred (DeltaN) 44
 
3.2.2.6 Fukui Indices (FIs) 45
 
3.3 Atomistic Simulations 45
 
3.3.1 Molecular Dynamics (MD) Simulations 46
 
3.3.1.1 Total Energy Minimization 46
 
3.3.1.2 Ensemble 47
 
3.3.1.3 Force Fields 47
 
3.3.1.4 Periodic Boundary Condition 47
 
3.3.2 Monte Carlo (MC) Simulations 48
 
3.3.3 Parameters Derived from MD and MC Simulations of Corrosion Inhibition 48
 
3.3.3.1 Interaction and Binding Energies 49
 
3.3.3.2 Radial Distribution Function 50
 
3.3.3.3 Mean Square Displacement, Diffusion Coefficient, and Fractional Free Volume 50
 
Acknowledgments 51
 
Suggested Reading 51
 
References 51
 
4 Organ1c and Inorgan1c Corros1on Inh1b1tors: A Compar1son 59
Goncagül Serdaroglu and Savas' Kaya
 
4.1 Introduction 59
 
4.2 Corrosion Inhibitors 61
 
4.2.1 Organic Corrosion Inhibitors 61
 
4.2.1.1 Azoles 62
 
4.2.1.2 Azepines 63
 
4.2.1.3 Pyridine and Azines 64
 
4.2.1.4 Indoles 65
 
4.2.1.5 Quinolines 66
 
4.2.1.6 Carboxylic Acid and Biopolymers 67
 
4.2.1.7 Inorganic Corrosion Inhibitors 68
 
4.2.1.8 Anodic Inhibitors 69
 
4.2.1.9 Cathodic Inhibitors 69
 
Referenc

About the author

Chandrabhan Verma, PhD, is Post-Doctoral Fellow, Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia. He is a member of American Chemical Society (ACS) and is the author of several research and review articles in peer-reviewed international journals.
Chaudhery Mustansar Hussain, PhD, is Adjunct Professor, Academic Advisor, and Director of Chemistry and EVSC Laboratories, New Jersey Institute of Technology (NJIT), USA. Dr. Hussain is the author of numerous papers in peer-reviewed journals as well as of several scientific monographs and handbooks in his research areas. Eno E. Ebenso, PhD, is Full Professor, Institute for Nanotechnology and Water Sustainability, College of Science, Engineering and Technology, University of South Africa, Johannesburg, South Africa. Professor Ebenso is the author of more than 450 peer-reviewed journal articles in peer-reviewed journals and is the recipient of several national and international awards for his academic achievements.

Summary

Provides comprehensive coverage of organic corrosion inhibitors used in modern industrial platforms, including current developments in the design of promising classes of organic corrosion inhibitors

Corrosion is the cause of significant economic and safety-related problems that span across industries and applications, including production and processing operations, transportation and public utilities infrastructure, and oil and gas exploration. The use of organic corrosion inhibitors is a simple and cost-effective method for protecting processes, machinery, and materials while remaining environmentally acceptable. Organic Corrosion Inhibitors: Synthesis, Characterization, Mechanism, and Applications provides up-to-date coverage of all aspects of organic corrosion inhibitors, including their fundamental characteristics, synthesis, characterization, inhibition mechanism, and industrial applications.

Divided into five sections, the text first covers the basics of corrosion and prevention, experimental and computational testing, and the differences between organic and inorganic corrosion inhibitors. The next section describes various heterocyclic and non-heterocyclic corrosion inhibitors, followed by discussion of the corrosion inhibition characteristics of carbohydrates, amino acids, and other organic green corrosion inhibitors. The final two sections examine the corrosion inhibition properties of carbon nanotubes and graphene oxide, and review the application of natural and synthetic polymers as corrosion inhibitors. Featuring contributions by leading researchers and scientists from academia and industry, this authoritative volume:
* Discusses the latest developments and issues in the area of corrosion inhibition, including manufacturing challenges and new industrial applications
* Explores the development and implementation of environmentally-friendly alternatives to traditional toxic corrosion inhibitors
* Covers both established and emerging classes of corrosion inhibitors as well as future research directions
* Describes the anticorrosive mechanisms and effects of acyclic, cyclic, natural, and synthetic corrosion inhibitors

Offering an interdisciplinary approach to the subject, Organic Corrosion Inhibitors: Synthesis, Characterization, Mechanism, and Applications is essential reading for chemists, chemical engineers, researchers, industry professionals, and advanced students working in fields such as corrosion inhibitors, corrosion engineering, materials science, and applied chemistry.

Product details

• Authors: Eb, Eno E. Ebenso, Chaudhery Mustansa Hussain, Chaudhery Mustansar Hussain, C Verma, Chandrabha Verma, Chandrabhan Verma, Chandrabhan (King Fahd University of Petrol Verma, Chandrabhan Hussain Verma
• Assisted by: Eno E Ebenso (Editor), Eno E. Ebenso (Editor), Chaudhery Mustansar Hussain (Editor), Hussain Chaudhery Mustansar (Editor), Chaudhery Mustansar Hussain (Editor), Chandrabhan Verma (Editor)
• Publisher: Wiley, John and Sons Ltd
• Languages: English
• Product format: Hardback
• Released: 31.01.2022
• EAN: 9781119794486
• ISBN: 978-1-119-79448-6
• No. of pages: 528
• Subjects: Natural sciences, medicine, IT, technology > Technology > General, dictionaries; Chemie, Organische Chemie, Korrosion, ORGANIC CHEMISTRY, Korrosionsschutz, chemistry, Materialwissenschaften, Industrial Chemistry, corrosion, Materials science, Technische u. Industrielle Chemie