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Science of Synthesis: Free Radicals: Fundamentals and Applications in Organic Synthesis 1

English · Hardback

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Radically enhance your progress in organic synthesis

Radical chemistry has undergone a renaissance in recent years. These two volumes will make the key developments accessible to a broad range of organic chemists. They cover both the generation of radicals and their use. The editors, Prof. Louis Fensterbank and Dr. Cyril Ollivier, are experts in radical chemistry and its application to organic synthesis.

Find out all about the generation and use of radicals

The two-volume set describes the fundamentals of radical chemistry and its application in organic synthesis. It includes practical examples of the generation of a variety of organic radicals. You will find critically reviewed, reliable and ready-to-use information on the use of radicals in:
- "single-electron transfer"
- "hydrogen-atom transfer"
- radical functionalization and
- cross-coupling processes.

By understanding the fundamental reactivities of radicals, they can be harnessed for atom-efficient and green reactions.

List of contents

Introduction: Radicals, from Gomberg to Planet Mars
1.1 Improving Radical Persistence through Confinement: A Survey
1.2 Nitroxides in Organic Synthesis
1.3 Modelling Radicals and Their Reactivities
1.4 Electron Catalysis
1.5 Photochemistry and Radical Generation: Approaches in Mechanism Elucidation
1.6 Sulfur-, Selenium-, and Silicon-Centered Radicals
1.7 Phosphorus-Centered Radicals
1.8 Nitrogen-Centered Radicals
1.9 Oxygen-Centered Radicals
1.10 Boron-Centerd Radicals
1.11 Generation of Radicals from Organoboranes
1.12 Intermolecular Radical C H Functionalization
1.13 Intramolecular Hydrogen-Atom Transfer
1.14 Palladium(I)-Mediated Reactions

Summary

Radically enhance your progress in organic synthesisRadical chemistry has undergone a renaissance in recent years. These two volumes will make the key developments accessible to a broad range of organic chemists. They cover both the generation of radicals and their use. The editors, Prof. Louis Fensterbank and Dr. Cyril Ollivier, are experts in radical chemistry and its application to organic synthesis.Find out all about the generation and use of radicalsThe two-volume set describes the fundamentals of radical chemistry and its application in organic synthesis. It includes practical examples of the generation of a variety of organic radicals. You will find critically reviewed, reliable and ready-to-use information on the use of radicals in:"single-electron transfer"hydrogen-atom transfer"radical functionalization andcross-coupling processes.By understanding the fundamental reactivities of radicals, they can be harnessed for atom-efficient and green reactions.

Product details

Assisted by Louis Fensterbank (Editor), Cyril Ollivier (Editor)
Publisher Thieme, Stuttgart
 
Languages English
Product format Hardback
Released 07.07.2021
 
EAN 9783132435520
ISBN 978-3-13-243552-0
No. of pages 768
Dimensions 186 mm x 53 mm x 270 mm
Weight 1640 g
Series Science of Synthesis
Subjects Natural sciences, medicine, IT, technology > Chemistry > Organic chemistry

Chemie, Catalysis, cross coupling, "single electron transfer", radical polymerization, photoredox reactions, "hydrogen atom transfer"

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