Molecular Constants Mostly from Infrared Spectroscopy - Non-linear Triatomic Molecules, Part 2: O3

The present subvolume provides evaluated infrared spectroscopic data on O₃ (Ozone) and is dedicated to all available molecular constants in the electronic ground state, of the 18 isotopomers. It is made of separate chapters. The first one succinctly reports molecular theories and equations, based on which most of the evaluated data given in the other chapters are established. Title of each data chapter indicates which data is reported (vibrational states, vibrational energy, band centers, harmonic frequencies, anharmonic constants, rotational and centrifugal distortion constants, resonance coupling constants, potential energy function, force constants, dipole transition moment, integrated band intensity, line shape parameters...). The isotopic identification, the natural isotopic abundance, and the cited bibliographic references are also given in each data chapter.

List of contents

Introduction.- General remarks.- Energy level vibrational assignment. Normal modes and Local modes.- Rotational assignment.- Polyads. Energy level vibrational interactions.- A-reduced Watson-type rotational Hamiltonian.- S-reduced Watson-type rotational Hamiltonian.- Perturbation-theory free, Jensen MORBID Hamiltonian.- Jensen's PES determined by variational calculation of rotation-vibration energies, with MORBID Hamiltonian.- Force field parameters.- Dipole moment.- Line profiles.- References.- O₃ data.

Summary

The present subvolume provides evaluated infrared spectroscopic data on O₃ (Ozone) and is dedicated to all available molecular constants in the electronic ground state, of the 18 isotopomers. It is made of separate chapters. The first one succinctly reports molecular theories and equations, based on which most of the evaluated data given in the other chapters are established. Title of each data chapter indicates which data is reported (vibrational states, vibrational energy, band centers, harmonic frequencies, anharmonic constants, rotational and centrifugal distortion constants, resonance coupling constants, potential energy function, force constants, dipole transition moment, integrated band intensity, line shape parameters…). The isotopic identification, the natural isotopic abundance, and the cited bibliographic references are also given in each data chapter.

Product details

• Authors: Guy Guelachvili, Nathalie Picqué
• Assisted by: Guy Guelachvili (Editor)
• Publisher: Springer, Berlin
• Languages: English
• Product format: Hardback
• Released: 01.01.2019
• EAN: 9783662579596
• ISBN: 978-3-662-57959-6
• No. of pages: 531
• Dimensions: 193 mm x 33 mm x 270 mm
• Illustrations: XXII, 531 p.
• Series: Molecules and Radicals; Landolt-Börnstein: Numerical Data and Functional Relationships in Science and Technology - New Series
• Subjects: Natural sciences, medicine, IT, technology > Chemistry > Physical chemistry; C, Potential, Kernphysik, Microscopy, Structure, spectroscopy, Spectroscopy and Microscopy, Nuclear physics, Physics and Astronomy, Scientific equipment, experiments & techniques, Atomic structure, Molecular structure, Atomic/Molecular Structure and Spectra, Atomic and Molecular Structure and Properties, spectroscopic parameter, molecular constant, vibrational state, line shape, molecular parameter, potential energy, line intensity, vibrational energy