Energy-Level Control at Hybrid Inorganic/Organic Semiconductor Interfaces

This work investigates the energy-level alignment of hybrid inorganic/organic systems (HIOS) comprising ZnO as the major inorganic semiconductor. In addition to offering essential insights, the thesis demonstrates HIOS energy-level alignment tuning within an unprecedented energy range. (Sub)monolayers of organic molecular donors and acceptors are introduced as an interlayer to modify HIOS interface-energy levels. By studying numerous HIOS with varying properties, the author derives generally valid systematic insights into the fundamental processes at work. In addition to molecular pinning levels, he identifies adsorption-induced band bending and gap-state density of states as playing a crucial role in the interlayer-modified energy-level alignment, thus laying the foundation for rationally controlling HIOS interface electronic properties. The thesis also presents quantitative descriptions of many aspects of the processes, opening the door for innovative HIOS interfaces and for future applications of ZnO in electronic devices. 

List of contents

Introduction.- Fundamentals.- Theory of Experimental Methods.- Methodology and Experimental Setups.- Results and Discussion.- Conclusion. 

Summary

This work investigates the energy-level alignment of hybrid inorganic/organic systems (HIOS) comprising ZnO as the major inorganic semiconductor. In addition to offering essential insights, the thesis demonstrates HIOS energy-level alignment tuning within an unprecedented energy range. (Sub)monolayers of organic molecular donors and acceptors are introduced as an interlayer to modify HIOS interface-energy levels. By studying numerous HIOS with varying properties, the author derives generally valid systematic insights into the fundamental processes at work. In addition to molecular pinning levels, he identifies adsorption-induced band bending and gap-state density of states as playing a crucial role in the interlayer-modified energy-level alignment, thus laying the foundation for rationally controlling HIOS interface electronic properties. The thesis also presents quantitative descriptions of many aspects of the processes, opening the door for innovative HIOS interfaces and for future applications of ZnO in electronic devices. 

Product details

• Authors: Raphael Schlesinger
• Publisher: Springer, Berlin
• Languages: English
• Product format: Paperback / Softback
• Released: 01.01.2018
• EAN: 9783319835501
• ISBN: 978-3-31-983550-1
• No. of pages: 211
• Dimensions: 156 mm x 236 mm x 14 mm
• Weight: 372 g
• Illustrations: XVIII, 211 p. 88 illus., 52 illus. in color.
• Series: Springer Theses; Springer Theses
• Subjects: Natural sciences, medicine, IT, technology > Physics, astronomy > Atomic physics, nuclear physics; B, Microscopy, spectroscopy, Spectroscopy and Microscopy, Optical and Electronic Materials, Physics and Astronomy, Electronic materials, Electronic devices & materials, Optical Materials, Spectrum analysis, spectrochemistry, mass spectrometry, Semiconductors, Scientific equipment, experiments & techniques, Interfaces (Physical sciences), Surface and Interface Science, Thin Films, Surface and Interface and Thin Film, Thin films, Surfaces (Physics)