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Zusatztext "...a well-written and timely piece of work for any scientists and engineers who work with solvents...and will be a valuable addition to their bookshelves." (Energy Sources! Vol. 26! 2004)"...well written and easy to read! very useful for a student audience...will introduce the subject to a wider audience..." (Organic Process Research & Development! Dec 2003) Informationen zum Autor Dave J. Adams is the author of Chemistry In Alternative Reaction Media , published by Wiley. Paul J. Dyson is the author of Chemistry In Alternative Reaction Media , published by Wiley. Stewart J. Tavener is the author of Chemistry In Alternative Reaction Media , published by Wiley. Klappentext At a time when environmental concerns are increasing, it's important that chemical processes are as environmentally friendly as possible. This book outlines various methods for producing inorganic and organic solvents without the use of traditional solvents that can have detrimental effects on the environment.* This is the first book to give extensive and exclusive coverage to the topic* Includes important environmental issuesThis book will appeal to anyone with an interest in organic synthesis; reaction chemistry; catalysis; and process development, and to undergraduate and graduate students of organic chemistry; catalysis; green chemistry; clean technology and environmental chemistry courses. Zusammenfassung At a time when environmental concerns are increasing, it's important that chemical processes are as environmentally friendly as possible. This book outlines various methods for producing inorganic and organic solvents without the use of traditional solvents that can have detrimental effects on the environment. Inhaltsverzeichnis Preface. Abbreviations and Acronyms. 1 Chemistry in Alternative Reaction Media. 1.1 Economic and Political Considerations. 1.2 Why Do Things Dissolve? 1.3 Solvent Properties and Solvent Classification. 1.3.1 Density. 1.3.2 Mass Transport. 1.3.3 Boiling Point, Melting Point and Volatility. 1.3.4 Solvents as Heat-Transfer Media. 1.3.5 Cohesive Pressure, Internal Pressure, and Solubility Parameter. 1.4 Solvent Polarity. 1.4.1 Dipole Moment and Dispersive Forces. 1.4.2 Dielectric Constant. 1.4.3 Electron Pair Donor and Acceptor Numbers. 1.4.4 Empirical Polarity Scales. 1.4.5 E NT and E T(30) Parameters. 1.4.6 Kamlet-Taft Parameters. 1.4.7 Hydrogen Bond Donor (HBD) and Hydrogen Bond Acceptor (HBA) Solvents. 1.5 The Effect of Solvent Polarity on Chemical Systems. 1.5.1 The Effect of Solvent Polarity on Chemical Reactions. 1.5.2 The Effect of Solvent Polarity on Equilibria. 1.6 W hat is Required from Alternative Solvent Strategies? References. 2 Multiphasic Solvent Systems. 2.1 An Introduction to Multiphasic Chemistry. 2.1.1 The Traditional Biphasic Approach. 2.1.2 Temperature Dependent Solvent Systems. 2.1.3 Single- to Two-Phase Systems. 2.1.4 Multiphasic Systems. 2.2 Solvent Combinations. 2.2.1 Water. 2.2.2 Fluorous Solvents. 2.2.3 Ionic Liquids. 2.2.4 Supercritical Fluids and Other Solvent Combinations. 2.3 Benefits and Problems Associated with Multiphasic Systems. 2.3.1 Partially Miscible Liquids. 2.4 Kinetics of Homogeneous Reactions. 2.4.1 Rate is Independent of Stoichiometry. 2.4.2 Rate is Determined by the Probability of Reactants Meeting. 2.4.3 Rate is Measured by the Concentration of the Reagents. 2.4.4 Catalysed Systems. 2.5 Kinetics of Biphasic Reactions. 2.5.1 The Concentration of Reactants in Each Phase is Affected by Diffusion. 2.5.2 The Concentration...
