Cellulose Science and Technology - Chemistry, Analysis, and Applications

Informationen zum Autor Thomas Rosenau, PhD, is a professor at BOKU University Vienna, holding the Chair of Wood, Pulp and Fiber Chemistry and heading both the Division of Chemistry of Renewable Resources and the Austrian Biorefinery Center Tulln. Antje Potthast, PhD, is a professor in the Department of Chemistry and is the deputy head of both the Division of Chemistry of Renewable Resources and the Austrian Biorefinery Center Tulln. Johannes Hell, PhD, is a technical manager at a Viennese chocolate factory. Klappentext This book addresses both classic concepts and state-of-the-art technologies surrounding cellulose science and technology. Integrating nanoscience and applications in materials, energy, biotechnology, and more, the book appeals broadly to students and researchers in chemistry, materials, energy, and environmental science.* Includes contributions from leading cellulose scientists worldwide, with five Anselm Payen Cellulose Award winners and two Hayashi Jisuke Cellulose Award winners* Deals with a highly applicable and timely topic, considering the current activities in the fields of bioeconomies, biorefineries, and biomass utilization* Maximizes readership by combining fundamental science and application development Zusammenfassung This book addresses both classic concepts and state-of-the-art technologies surrounding cellulose science and technology. Integrating nanoscience and applications in materials! energy! biotechnology! and more! the book appeals broadly to students and researchers in chemistry! materials! energy! and environmental science.* Includes contributions from leading cellulose scientists worldwide! with five Anselm Payen Cellulose Award winners and two Hayashi Jisuke Cellulose Award winners* Deals with a highly applicable and timely topic! considering the current activities in the fields of bioeconomies! biorefineries! and biomass utilization* Maximizes readership by combining fundamental science and application development Inhaltsverzeichnis Author Biography xv List of Contributors xvii Preface xxiii Acknowledgements xxv 1 Aminocelluloses - Polymers with Fascinating Properties and Application Potential 1 Thomas Heinze, Thomas Elschner, and Kristin Ganske 1.1 Introduction 1 1.2 Amino-/ammonium Group Containing Cellulose Esters 2 1.2.1 (3-Carboxypropyl)trimethylammonium Chloride Esters of Cellulose 2 1.2.2 Cellulose-4-(N-methylamino)butyrate (CMABC) 7 1.3 6-Deoxy-6-amino Cellulose Derivatives 9 1.3.1 Spontaneous Self-assembling of 6-Deoxy-6-amino Cellulose Derivatives 10 1.3.2 Application Potential of 6-Deoxy-6-amino Cellulose Derivatives 13 1.4 Amino Cellulose Carbamates 21 1.4.1 Synthesis 21 1.4.2 Properties 22 Acknowledgment 24 References 24 2 Preparation of Photosensitizer-bound Cellulose Derivatives for Photocurrent Generation System 29 Toshiyuki Takano 2.1 Introduction 29 2.2 Porphyrin-bound Cellulose Derivatives 31 2.3 Phthalocyanine-bound Cellulose Derivatives 34 2.4 Squaraine-bound Cellulose Derivative 40 2.5 Ruthenium(II) Complex-bound Cellulose Derivative 42 2.6 Fullerene-bound Cellulose Derivative 44 2.7 Porphyrin-bound Chitosan Derivative 45 2.8 Conclusion 47 References 47 3 Synthesis of Cellulosic Bottlebrushes with Regioselectively Substituted Side Chains and Their Self-assembly 49 Keita Sakakibara, Yuji Kinose, and Yoshinobu Tsujii 3.1 Introduction 49 3.2 Strategy for Accomplishing Regioselective Grafting of Cellulose 52 3.3 Regioselective Introduction of the First Polymer Side Chain 55 3.3.1 Introduction of Poly(styrene) at O -2,3 Position of 6- O - p -Methoxytritylcellulose (1) 55 3.3.2 Introduction of ...

List of contents

Author Biography xv
 
List of Contributors xvii
 
Preface xxiii
 
Acknowledgements xxv
 
1 Aminocelluloses - Polymers with Fascinating Properties and Application Potential 1
Thomas Heinze, Thomas Elschner, and Kristin Ganske
 
1.1 Introduction 1
 
1.2 Amino-/ammonium Group Containing Cellulose Esters 2
 
1.2.1 (3-Carboxypropyl)trimethylammonium Chloride Esters of Cellulose 2
 
1.2.2 Cellulose-4-(N-methylamino)butyrate (CMABC) 7
 
1.3 6-Deoxy-6-amino Cellulose Derivatives 9
 
1.3.1 Spontaneous Self-assembling of 6-Deoxy-6-amino Cellulose Derivatives 10
 
1.3.2 Application Potential of 6-Deoxy-6-amino Cellulose Derivatives 13
 
1.4 Amino Cellulose Carbamates 21
 
1.4.1 Synthesis 21
 
1.4.2 Properties 22
 
Acknowledgment 24
 
References 24
 
2 Preparation of Photosensitizer-bound Cellulose Derivatives for Photocurrent Generation System 29
Toshiyuki Takano
 
2.1 Introduction 29
 
2.2 Porphyrin-bound Cellulose Derivatives 31
 
2.3 Phthalocyanine-bound Cellulose Derivatives 34
 
2.4 Squaraine-bound Cellulose Derivative 40
 
2.5 Ruthenium(II) Complex-bound Cellulose Derivative 42
 
2.6 Fullerene-bound Cellulose Derivative 44
 
2.7 Porphyrin-bound Chitosan Derivative 45
 
2.8 Conclusion 47
 
References 47
 
3 Synthesis of Cellulosic Bottlebrushes with Regioselectively Substituted Side Chains and Their Self-assembly 49
Keita Sakakibara, Yuji Kinose, and Yoshinobu Tsujii
 
3.1 Introduction 49
 
3.2 Strategy for Accomplishing Regioselective Grafting of Cellulose 52
 
3.3 Regioselective Introduction of the First Polymer Side Chain 55
 
3.3.1 Introduction of Poly(styrene) at O-2,3 Position of 6-O-p-Methoxytritylcellulose (1) 55
 
3.3.2 Introduction of Poly(ethylene oxide) at O-2,3 Position of 6-O-p-Methoxytritylcellulose (1) 57
 
3.4 Regioselective Introduction of the Second Polymer Side Chain 58
 
3.4.1 Introduction of Poly(styrene) at O-6 Position of 2,3-di-O-PEO Cellulose (5) via Grafting-from Approach 58
 
3.4.2 Introduction of Poly(styrene) at O-6 Position of 2,3-di-O-PEO Cellulose (5) via Grafting to Approach Combining Click Reaction 58
 
3.5 SEC-MALLS Study 61
 
3.6 Summary and Outlook 64
 
Acknowledgments 64
 
References 64
 
4 Recent Progress on Oxygen Delignification of Softwood Kraft Pulp 67
Adriaan R. P. van Heiningen, Yun Ji, and Vahid Jafari
 
4.1 Introduction and State-of-the-Art of Commercial Oxygen Delignification 67
 
4.2 Chemistry of Delignification and Cellulose Degradation 70
 
4.3 Improving the Reactivity of Residual Lignin 73
 
4.4 Improving Delignification/Cellulose Degradation Selectivity During
 
Oxygen Delignification 79
 
4.5 Improving Pulp Yield by Using Oxygen Delignification 90
 
4.6 Practical Implementation of High Kappa Oxygen Delignification 92
 
References 93
 
5 Toward a Better Understanding of Cellulose Swelling, Dissolution, and Regeneration on theMolecular Level 99
Thomas Rosenau, Antje Potthast, Andreas Hofinger,Markus Bacher, Yuko Yoneda, KurtMereiter, Fumiaki Nakatsubo, Christian Jäger, Alfred D. French, and Kanji Kajiwara
 
5.1 Introduction 99
 
5.2 Cellulose Swelling, Dissolution and Regeneration at the Molecular Level 102
 
5.2.1 The "Viewpoint of Cellulose" 109
 
5.2.2 The "Viewpoint of Cellulose Solvents" 113
 
5.3 Conclusion 118
 
References 120
 
6 Interaction ofWaterMolecules with Carboxyalkyl Cellulose 127
HitomiMiyamoto, Keita Sakakibara, IsaoWataoka, Yoshinobu Tsuji

Product details

• Authors: Johannes Hell, Antj Potthast, Antje Potthast, T Rosenau, Thoma Rosenau, Thomas Rosenau, Thomas Potthast Rosenau
• Assisted by: Johannes Hell (Editor), Antj Potthast (Editor), Antje Potthast (Editor), Thomas Rosenau (Editor), Rosenau Thomas (Editor)
• Publisher: Wiley, John and Sons Ltd
• Languages: English
• Product format: Hardback
• Released: 31.12.2018
• EAN: 9781119217589
• ISBN: 978-1-119-21758-9
• No. of pages: 480
• Subjects: Natural sciences, medicine, IT, technology > Chemistry > Organic chemistry; Chemie, Energie, Erneuerbare Energien, ENERGY, Renewable Energy, chemistry, Biopolymere, Cellulose, Polymer Science & Technology, Polymerwissenschaft u. -technologie, Biopolymers, Cellulose/Paper/Textile Chemistry, Cellulose-, Papier- u. Textilchemie