Inorganic Syntheses, Volume 33

New procedures and compounds for students and professionals in the field of inorganic chemistry The Inorganic Syntheses series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. In Volume 33, editor Dimitri Coucouvanis collects syntheses that present new or revised experimental procedures that are applicable to a variety of related compounds, as well as syntheses of individual compounds that are of interest or importance. Chapter topics are comprised of syntheses of selected supramolecules, useful reagents/ligands, solid state materials/clusters, and compounds of general interest, including mesityl-gold (I)complexes and zero valent binuclear nickel complexes, among many others
All the syntheses presented have been tested. Inorganic, organic, and organometallic chemists, as well as materials scientists, instructors, and graduate students will find the research, methods, and compounds contained here invaluable to their scientific pursuits.

List of contents

Chapter One SYNTHESES OF SELECTED SUPRAMOLECULES.

1. Toward Magnetic Building Blocks: Synthesis of a Planar Co(III)-cation Radical-cobalt(III) Complex of the Binucleating Ligand 1,2,4,5-Tetrakis(2-hydroxy-2-methylpropanamido)benzene.

2. A Luminescent Decanuclear Ruthenium(II) Polypyridine Complex: A Convergent Approach to a Dendritic Structure Employing the "Complexes as Metals/Complexes as Ligands" Synthetic Strategy.

3. Dodecatungstoaluminic Acid and Its Monolacunary and Mixed-Addendum Derivatives.

4. Supramolecular Complexes of BisBis(2,2'-bipyridine)osmium(II) and Ruthenium(II).

5. Binuclear Oxomolybdenum-Metalloporphyrin Complexes.

6. Iron Sandwich Polyoxoanion Compounds.

7. Dipyrryl and Porphyrinic Precursors to Supramolecular Conjugated (Porphinato)metal Arrays: Syntheses of Dipyrrylmethane and (5,15-diphenylporphinato)zinc(II).

8. Synthesis of Dodecaoxohexadecacarboxylatotetraaquo-dodecamanganese [Mn₁₂O₁₂(O₂CR)₁₆(H₂O)₄] (R = Me,Et,Ph,Cr) Complexes.

9. Use of Picolinehydroximate Complexes in Preparation of Uranyl and Lanthanide 15-Metallacrown-5: UO₂(NO₃)₂ [15-MCCu(II)N(pic)-15] and {Eu(NO₃)₂[15-MCCu(II)N(pic)-15]}NO₃.

10. Use of Salicyl- and Naphthoylhydroximate Complexes in Preparation of Manganese and Copper 12-Metallacrown-4 Complexes: Mn(II)(Acetate)₂ [Mn(III)(salicylhydroximate)]₄ and (Tetramethylammonium)₂ [Cu(II)₅ (naphthoylhydroximate)₄].

Chapter Two USEFUL REAGENTS AND LIGANDS.

11. Homoleptic Transition Metal Acetonitrile Cations with Tetrafluoroborate or Trifluoromethanesulfonate Anions.

12. Synthesis of [M^II(NCMe)₆]²⁺ (M = V,Cr,Mn,Fe,Co,Ni) Salts of Tetra[3,5-bis(trifluoromethyl)phenyl]borate.

13. Transition Metal p-Toluenesulfonates.

14. Salts of Binuclear Iron(II) and Iron(III) Dianions [(Fe₂C_l6)^2- and (Fe₂OC_l6)^2-].

15. Tetraethylammonium-Tetrathioperrhenate Et₄N(ReS₄).

16. Large-Scale Synthesis of Methyltrioxorhenium (CH₃ReO₃).

17. 4,5-Diaminocatechol: A Useful Building Block in Synthesis of Multimetallic Complexes.

18. A Convenient Synthesis of 1,5,9-Trithiacyclododecane (S₃C₉H₁₈).

Chapter Three SOLID-STATE MATERIALS AND CLUSTERS.

19. Synthesis of Quaternary Selenophosphates using Molten Salt Fluxes: Rb₈Hg₄(Se₂)₂(PSe₄)₄, K₄In₂(PSe₅)₂(P₂Se₆), Rb₄Ti₂(P₂Se₇)(P₂Se₉)₂, Rb₄U₄(Se)₂(Se₂)₄(PSe₄)₄.

20. Hydrothermal Synthesis of Sulfosalts: Ag₃AsS₃, Ag₃SbS₃, Ag₇SbS₆, Cu₁₂Sb₄S₁₃, CuInS₂, FeIn₂S₄.

21. Open-Framework Solids of the Vanadium Oxide-Phosphate System.

22. Sulfur-Bridged Incomplete Cubane-Type Molybdenum and Tungsten Aqua Ions.

23. Sulfur-Bridged Cubane Type Mixed-Metal Clusters with Mo₃MS₄ (M = Fe,Co,Ni,Cu,In,Sn) and W₃NiS₄ Cores.

24. Molybdenum and Tungsten Clusters as Aqua Ions [M₃Q₄(H₂O)₉]⁴⁺ (M = Mo,W; Q = S,Se) and Related Chalcogen-Rich Trinuclear Clusters.

Chapter Four COMPOUNDS OF GENERAL INTEREST.

25. The Diphenylmethylenethiophosphinate (MTP) Ligand in Gold(I), Platinum(II), Lead(II), Thallium(I), and Mercury(II) Complexes, sym-Au₂(MTP)₂, (PPN)[Au(MTP)₂], Au₂Pt(MTP)₄, Au₂Pb(MTP)₄, AuTl(MTP)₄, Hg(MTP)₂, Hg(MTP)₂(AuCl)₂, and Hg^IIAu^I(MTP)₂Au^IIIC_l4.

26. Mesityl-gold(I) Complexes.

27. An Improved Synthesis of cis-Dithiocyanato-bis(4,4'-dicarboxy-2,2'-bpy) Ru(II) Sensitizer.

28. Dimethylsulfoxide Complexes of Platinum(II): K[PtCl₃(Me₂SO)], cis-[PtCl₂L(Me₂SO)] (L = Me₂SO,MeCN), [PtCl(¿-Cl)(Me₂SO)]₂, and [Pt(Me₂SO)₄](CF₃SO₃)₂.

29. Tetrasulfur-tetranitride (S₄N₄).

30. Hydrotris(methimazolyl)borate.

31. Arsenic(III)bromide.

32. Dichlorodioxo-bis(triphenylphosphine oxide)uranium(VI) [UO₂C_l2(OPPh₃)₂].

33. Chlorohydro-tris(pyrazol-1-yl)borato-bis(triphenylphosphine) ruthenium(II) {RuCl[k³-HB(pz)](PPh₃)₂} (pz = pyrazol-1-yl).

34. Octacarbonyl-di-¿-hydridodirhenium [Re₂(¿-H)₂(CO)₈].

35. Zero-Valent Binuclear Nickel Complexes.

36. Preparation of a Synthetic Ribonuclease: The Europium(III) Complex of 1-(4-nitrobenzyl)-4,7,10-Tris(carbamoylmethyl)-1,4,7,10- tetraazacyclododecane.

37. Carbonyl Halide Tungsten(II) Complexes of Tris(3,5-dimethylpyrazolyl)hydroborate.

38. A Luminescent Complex of Re(I): fac-[Re(CO)₃(bpy)(py)](CF₃SO₃) (bpy = 2.2'-bipyridine; py = pyridine).

39. RSi(OH)₃ and RSi(NH₂)₃ [R = 2,6-iPr₂C₆H₃N(SiMe₃)]: Synthesis of Stable Organosilanes with Three Functional Groups.

40. Fluorination with Me₃SnF: Synthesis of Cyclopentadienyl-Substituted Group 4 Metal Fluoride Complexes.

41. Seven-Coordinate [MI₂(CO)₃(NCMe)₂], [MI₂(CO)₃(NCMe)(PPh₃)], and Alkyne [MI₂(CO)(NCMe)(¿²-RC₂R)₂] Complexes of Molybdenum(II) and Tungsten(II).

42. Chlorothiocarbonyl-bis(triphenylphosphine)iridium(I) [IrCl(CS)(PPh₃)₂].

Contributor Index.

Subject Index.

Formula Index.

About the author

DIMITRI COUCOUVANIS, PhD, is Professor of Chemistry at the University of Michigan.

Summary

This series provides inorganic chemists with detailed procedures for the preparation of important and timely compounds. This volume continues to report such procedures with an up-to-date selection of contributions by internationally-recognized researchers.

Product details

• Authors: Dimitri Coucouvanis
• Assisted by: Dimitri Coucouvanis (Editor)
• Publisher: Wiley
• Languages: English
• Product format: Hardback
• Released: 02.05.2002
• EAN: 9780471208259
• ISBN: 978-0-471-20825-9
• No. of pages: 304
• Dimensions: 157 mm x 235 mm x 21 mm
• Weight: 596 g
• Series: Inorganic Syntheses; Inorganic Syntheses
• Subject: Natural sciences, medicine, IT, technology > Chemistry > Inorganic chemistry