Iridium Complexes in Organic Synthesis

Hydrierungen, Hydroaminierungen, Cycloadditionen - bis hin zu Reaktionen von Nanopartikeln: Dieser Band beleuchtet alle Möglichkeiten des Einsatzen von Iridium in der organischen Chemie. Einen besonderen Schwerpunkt bilden dabei Katalysatoren für die enantioselektive Synthese.

List of contents

APPLICATION OF IRIDIUM CATALYSTS IN THE FINE CHEMICALS INDUSTRYIntroductionIndustrial Requirements for Applying CatalystsEnantioselective Hydrogenation of C=N BondsEnantioselective Hydrogenation of C=C BondsMiscellaneous Catalytic Applications with Industrial PotentialDIHYDRIDO IRIDIUM TRIISOPROPYLPHOSPHINE COMPLEXES: FROM ORGANOMETALLIC CHEMISTRY TO CATALYSISIntroduction[Ir(COD)(NCMe)(PR3)]BF4 (PR=PiPr3, PMe3) and Related Complexes as Catalyst Precursors: Is 1,5-Cyclo-Octadiene an Innocent and Removable Ligand?The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkene Hydrogenation CatalystsThe Dihydrido Iridium Triisoprpylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkyne Hydrogenation CatalystsDihydrido Arene Iridium Triisopropylphosphine ComplexesDihydrido Iridium Triisopropylphosphine Complexes as Imine Hydrogenation CatalystsIRIDIUM N-HETEROCYCLIC CARBENE COMPLEXES AND THEIR APPLICATON AS HOMOGENEOUS CATALYSTSIntroductionTypes or Ir-NHC and ReactivityCatalysis with Ir-NHCsIRIDIUM-CATALYZED C=O HYDROGENATIONIntroductionHomogeneous C=O HydrogenationsHeterogeneous, Supported and Biocatalytic HydrogenationsCATALYTIC ACTIVITY OF Cp* IRIDIUM COMPLEXES IN HYDROGEN TRANSFER REACTONSIntroductionHydrogen Transfer Oxidation of Alcohols (Oppenauer-Type Oxidation)Transfer Hydrogenation of Unsaturated CompoundsAsymmetric Synthesis Based on Hydrogen TransferHydrogen Transfer Reactions in Aqueous MediaCarbon-Nitrogen Bond Formation Based on Hydrogen TransferCarbon-Carbon Bond Formation Based on Hydrogen TransferCarbon-Oxygen Bond Formation Based on Hydrogen TransferDehydrogenative Oxidation of AlcoholsIRIDIUM-CATALYZED HYDROAMINATIONIntroductionIridium-Catalyzed Olefin Hydroamination (OHA)Iridium-Catalyzed Alkyne Hydroamination (ASA)Proposed MechanismsComplexes and Reactions of Ir Relevant to HydroaminationIRIDIUM-CATALYZED BORON-ADDITIONIntroductionIridium-Boryl ComplexesHydroborationDiborationBorylationIRIDIUM-CATALYZED METHANOL CARBONYLATIONIntroductionRhodium-Based ProcessesIridium Reactivity in the Methanol Carbonylation ReactionThe Iridium-Based Cativa ProcessThe Iridium-Platinum-Based ProcessThe Iridium-Cocatalyst Mechanism, and Conclusion AcknowledgmentsIRIDIUM-CATALYZED ASYMMETRIC ALLYLIC SUBSTITUTIONSIntroductionIr-Catalyzed Allylic Substitutions: FundamentalsC-NucleophilesN-NucleophilesO-NucleophilesSynthesis of Biologically Active Compounds via Allylic SubstitutionIRIDIUM-CATALYZED COUPLING REACTIONSIntroductionIridium-Catalyzed Dimerization and Cyclotrimerization of AlkynesIridium-Catalyzed, Three-Component Coupling Reactions of Aldehydes, Amines and AlkynesHead-to-Tail Dimerization of AcrylatesA Novel Synthesis of Vinyl Ethers via an Unusual Exchange ReactionIridium-Catalyzed Allylic SubstitutionAlkylation of Ketones with AlcoholsN-Alkylation of AminesOxidative Dimerization of Primary Alcohols to estersIridium-Catalyzed Addition of Water and Alcohols to Terminal AlkynesIridium-Catalyzed Direct Arylation of Aromatic C-H BondsIridium-Catalyzed Anti-Markovnikov Olefin ArylationIridium-Catalyzed Silylation and Borylation of Aromatic C-H BondsMiscellaneous Reactions Catalyzed by Iridium ComplexesIRIDIUM-CATALYZED CYCLOADDITIONSIntroduction[2+2+2] CycloadditionEnantioselective [2+2+2] Cycloaddition[2+2+1] Cycloaddition[4+2] and [5+1] CycloadditionCycloisomerizationIr(III)-Catalyzed CyclizationsMiscellaneous CycloadditionsPINCER-TYPE IRIDIUM COMPLEXES FOR ORGANIC TRANSFORMATIONSIntroductionIridium PCP-Catalyzed Activation of C(sp3)-H Bonds in Unfunctionalized AlkanesArene C(sp2)-H and Alyne C(sp1)-H Bond ActivationC-E Bond ActivationAmmonia Borane DehydrogenationIRIDIUM-MEDIATED ALKANE DEHYDROGENATIONIntroductionAlkane C-H Activation with Ir DerivativesAlkane Dehydrogenation with Ir ComplexesAlkane Dehydrogenation Catalyzed by Ir Pincer ComplexesTRANSFORMATIONS OF (ORGANO)SILICON COMPOUNDS CATALYZED BY IRIDIUM COMPLEXESIntroductionHydrosilylation and Dehydrogenative Silylation of Carbon-Carbon Multiple BondsAsymmetric Hydrosilylation of Ketones and IminesTransformation of Organosilicon Compounds in the Presence of Carbon MonoxideSilylation of Aromatic Carbon-Hydrogen BondsSilylation of Alkenes with VinylsilanesAlcoholysis and Oxygenation of HydrosilanesIsomerization of Silyl OlefinsAddition of Silylacetglenes C-H Bonds into IminesCATALYTIC PROPERTIES OF SOLUBLE IR IDIUM NANOPARTICLESIntroductionSynthesis of Soluble Iridium NanoparticlesKinetic Studies of Iridium Nanoparticle Formation: The Autocatalytic MechanismCatalytic Applications of Soluble Iridium Nanoparticles

About the author

Luis A. Oro is the head of the Homogeneous Catalysis Institute and professor of Inorganic Chemistry in the University of Zaragoza. His main research interests are in organometallic chemistry of platinum group metals where he has coauthored about 500 scientific contributions, and edited several books. He is member of the Interantional Advisory Board of Angewandte Chemie, and other international journals. He has received several scientific awards, including the Humboldt award, King Jaime prize, Solvay prize and Sacconi Medal. He is Doctor Honoris Causae by Rennes University. He is also member of the Deutsche Akademie der Naturforscher Leopoldina, the Academia Europaea, and foreign member of the Académie des Sciences.

Carmen Claver is Professor of Inorganic Chemistry at the University Rovira I Virgili in Tarragona (Spain). She has co-authored about 200 scientific contributions in the field of enantioselective synthesis. She has also participated in the edition and publication of several books. She has received several scientific awards, being recognised in 2003 as distinguished research for the Catalan Government.

Summary

Hydrierungen, Hydroaminierungen, Cycloadditionen - bis hin zu Reaktionen von Nanopartikeln: Dieser Band beleuchtet alle Möglichkeiten des Einsatzen von Iridium in der organischen Chemie. Einen besonderen Schwerpunkt bilden dabei Katalysatoren für die enantioselektive Synthese.

Report

?This book provides good coverage of an increasingly important area and will be well worth reading by anyone interested in metal-catalyzed organic synthesis.? ( The Journal of the American Chemical Society , July 2009)
?Both academic and industrial practitioners of transition-metal catalysis and organometallic chemistry will find this volume to be a very useful addition to their bookshelves.? ( Angewandte Chemie International Edition , June 2009)

Product details

• Authors: Carmen Claver, Luis A. Oro
• Assisted by: Lui A Oro (Editor), Luis A Oro (Editor), CLAVER (Editor), Claver (Editor), Carmen Claver (Editor), Luis A. Oro (Editor)
• Publisher: Wiley-VCH
• Languages: English
• Product format: Hardback
• Released: 31.03.2015
• EAN: 9783527319961
• ISBN: 978-3-527-31996-1
• No. of pages: 396
• Dimensions: 179 mm x 248 mm x 27 mm
• Weight: 920 g
• Illustrations: 386 SW-Abb., 8 Farbabb., 28 Tabellen
• Subjects: Natural sciences, medicine, IT, technology > Chemistry > Organic chemistry; Chemie, Organische Chemie, ORGANIC CHEMISTRY, Katalyse, chemistry, Catalysis, Organische Synthese, Methods - Synthesis & Techniques, Organische Chemie / Methoden, Synthesen, Verfahren, Coordination Chemistry, Koordinationschemie