Metal-Organic Frameworks - Applications from Catalysis to Gas Storage

An international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors.From the Contents:- Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future- Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification- Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks- Separation and purification of gases by MOFs- Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption- Manufacture of MOF thin films on structured supports for separation and catalysis- Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications- Separation of xylene isomers- Metal-Organic Frameworks as Catalysts for Organic Reactions- Biomedical applications of Metal Organic Frameworks- Metal Organic Frameworks for Biomedical Imaging- Luminescent Metal-Organic Frameworks- Deposition of thin films for sensor applications- Industrial MOF Synthesis- MOF shaping and immobilisationA must-have for every scientist in the field.

List of contents

PrefacePART I: Design of Multifunctional Porous MOFsDESIGN OF POROUS COORDINATION POLYMER/METAL-ORGANIC FRAMEWORKS: PAST, PRESENT AND FUTUREIntroductionBackground and Ongoing Chemistry of Porous Coordination PolymersMultifunctional FrameworksPreparation of Multifunctional FrameworksPerspectivesDESIGN OF FUNCTIONAL METAL-ORGANIC FRAMEWORKS BY POST-SYNTHETIC MODIFICATIONBuilding a MOFs Toolbox by Post-Synthetic ModificationPost-Functionalization of MOFs by Host-Guest InteractionsPost-Functionalization of MOFs Based on Coordination ChemistryPost-Functionalization of MOFs by Covalent BondsTandem Post-Modification for the Immobilization of Organometallic CatalystsCritical AssessmentConclusionPART II: Gas Storage and Separation ApplicationsTHERMODYNAMIC METHODS FOR PREDICTION OF GAS SEPARATION IN FLEXIBLE FRAMEWORKSIntroductionTheoretical BackgroundMolecular Simulation MethodsAnalytical Methods Based on Experimental DataOutlookSEPARATION AND PURIFICATION OF GASES BY MOFSIntroductionGeneral Principles of Gas Separation and PurificationMOFs for Separation and Purification ProcessesConclusions and PerspectivesOPPORTUNITIES FOR MOFS IN CO2 CAPTURE FROM FLUE GASES, NATURAL GAS, AND SYNGAS BY ADSORPTIONIntroductionGeneral Introduction to Pressure Swing AdsorptionProduction of H2 from SyngasCO2 Removal from Natural GasPost-Combustion CO2 CaptureMOFsConclusionsMANUFACTURE OF MOF THIN FILMS ON STRUCTURED SUPPORTS FOR SEPARATION AND CATALYSISAdvantages and Limitations of Membrane Technologies for Gas and Liquid SeparationMechanisms of Mass Transport and SeparationSynthesis of Molecular Sieve MembranesApplication of MOF MembranesLimitationsConclusions and OutlookRESEARCH STATUS OF METAL-ORGANIC FRAMEWORKS FOR ON-BOARD CRYO-ADSORPTIVE HYDROGEN STORAGE APPLICATIONSIntroduction - Research Problem and SignificanceMOFs as Adsorptive Hydrogen Storage OptionsExperimental Techniques and Methods for Performance and Thermodynamic Assessment of Porous MOFs for Hydrogen StorageMaterial Research ResultsFrom Laboratory-Scale Materials to EngineeringConclusionPART III: Bulk Chemistry ApplicationsSEPARATION OF XYLENE ISOMERSXylene Separation: Industrial Processes, Adsorbents, and Separation PrinciplesProperties of MOFs Versus Zeolites in Xylene SeparationsSeparation of Xylenes Using MIL-47 and MIL-53ConclusionsMETAL-ORGANIC FRAMEWORKS AS CATALYSTS FOR ORGANIC REACTIONSIntroductionMOFs with Catalytically Active Metal Nodes in the FrameworkCatalytic Functionalization of Organic Framework LinkersHomochiral MOFsMOF-Encapsulated Catalytically Active GuestsMesoporous MOFsConclusionsPART IV: Medical ApplicationsBIOMEDICAL APPLICATIONS OF METAL-ORGANIC FRAMEWORKSIntroductionMOFs for BioapplicationsTherapeuticsDiagnosticsFrom Synthesis of Nanoparticles to Surface Modification and ShapingDiscussion and ConclusionMETAL-ORGANIC FRAMEWORKS FOR BIOMEDICAL IMAGINGIntroductionGadolinium Carboxylate NMOFsManganese Carboxylate NMOFsIron Carboxylate NMOFs: The MIL FamilyIodinated NMOFs: CT Contrast AgentsLanthanide Nucleotide NMOFsGuest Encapsulation within NMOFsConclusionPART V: Physical ApplicationsLUMINESCENT METAL-ORGANIC FRAMEWORKSIntroductionLuminescence TheoryLigand-Based LuminescenceMetal-Based LuminescenceGuest-Induced LuminescenceApplications of Luminescent MOFsConclusionDEPOSITION OF THIN FILMS FOR SENSOR APPLICATIONSIntroductionLiterature SurveySignal Transduction ModesConsiderations in Selecting MOFs for Sensing ApplicationsMOF Thin Film Growth: Methods, Mechanisms, and LimitationsConclusions and PerspectivesPART VI: Large-Scale Synthesis and Shaping of MOFsINDUSTRIAL MOF SYNTHESISIntroductionRaw MaterialsSynthesisShapingApplicationsConclusion and OutlookMOF SHAPING AND IMMOBILISATIONIntroductionMOF@Fiber Composite MaterialsRequirements of Adsorbents for Individual ProtectionMOFs in Monolithic Structures

About the author

David Farrusseng received his BSc in chemistry from the University of Montpellier (France) under the supervision of Prof. R. Corriu. In 1999, he got his PhD in Materials Science at the European Institute of Membranes in Montpellier under the guidance of Drs. A. Julbe and C. Guizard. He joined as post-doc the group of Prof. F. Schüth at the MPI für Kohlenforschung (Germany). In 2001, he was appointed CNRS researcher at IRCELYON in the group of Dr. C. Mirodatos. He is currently group leader at IRCELYON. His research activities focus on the design of materials for original catalytic and separation processes and on the development of high-throughput approaches for which he was awarded in 2008 by the French Chemical Society. He is author of approximately 90 peer-reviewed publications and 15 patents.

Summary

An international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors.

From the Contents:
- Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future
- Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification
- Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks
- Separation and purification of gases by MOFs
- Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption
- Manufacture of MOF thin films on structured supports for separation and catalysis
- Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications
- Separation of xylene isomers
- Metal-Organic Frameworks as Catalysts for Organic Reactions
- Biomedical applications of Metal Organic Frameworks
- Metal Organic Frameworks for Biomedical Imaging
- Luminescent Metal-Organic Frameworks
- Deposition of thin films for sensor applications
- Industrial MOF Synthesis
- MOF shaping and immobilisation

A must-have for every scientist in the field.

Product details

• Authors: David Farrusseng
• Assisted by: Davi Farrusseng (Editor), David Farrusseng (Editor)
• Publisher: Wiley-VCH
• Languages: English
• Product format: Hardback
• Released: 31.03.2015
• EAN: 9783527328703
• ISBN: 978-3-527-32870-3
• No. of pages: 392
• Dimensions: 1760 mm x 2470 mm x 29 mm
• Weight: 922 g
• Illustrations: 159 SW-Abb., 26 Farbabb., 28 Tabellen
• Subjects: Natural sciences, medicine, IT, technology > Chemistry > Inorganic chemistry; Chemie, Nanotechnologie, Anorganische Chemie, Energie, ENERGY, Katalyse, chemistry, Catalysis, Chemical Engineering, chemische Verfahrenstechnik, Nanotechnology, Inorganic Chemistry, Nanomaterialien, Nanomaterials, Wasserstoff, Batterien u. Brennstoffzellen, Hydrogen, Batteries & Fuel Cells, Stofftrennverfahren, Separations, Metallorganische Verbindungen, MOF