Cooperative Catalysis - Designing Efficient Catalysts for Synthesis

Written by experts in the field, this is a much-needed overview of the rapidly emerging field of cooperative catalysis.The authors focus on the design and development of novel high-performance catalysts for applications in organic synthesis (particularly asymmetric synthesis), covering a broad range of topics, from the latest progress in Lewis acid / Brønsted base catalysis to e.g. metal-assisted organo catalysis, cooperative metal/enzyme catalysis, and cooperative catalysis in polymerization reactions and on solid surfaces. The chapters are classified according to the type of cooperating activating groups, and describe in detail the different strategies of cooperative activation, highlighting their respective advantages and pitfalls. As a result, readers will learn about the different concepts of cooperative catalysis, their corresponding modes of operation and their applications, thus helping to find a solution to a specific synthetic catalysis problem.

List of contents

LEWIS ACID - BRØNSTED BASE CATALYSISIntroductionLewis Acid - Brønsted Base Catalysis in MetalloenzymesHard Lewis Acid - Brønsted Base Cooperative CatalysisSoft Lewis Acid - Brønsted Base Cooperative CatalysisConclusionLEWIS ACID - LEWIS BASE CATALYSISIntroductionLewis Acid and Lewis Base ActivationAddition to Carbonyl CompoundsCondensation ReactionsMorita-Baylis-Hillman ReactionsEpoxide OpeningsCyclization ReactionsPolymerizationsConclusions and OutlookCOOPERATING LIGANDS IN CATALYSISIntroductionChemically Active Ligands Assisting a Metal-Localized Catalytic ReactionRedox-Active Ligands Assisting Metal-Based CatalystsSummaryCOOPERATIVE ENAMINE-LEWIS ACID CATALYSISIntroductionReactions Developed through Cooperative Enamine-Lewis Acid CatalysisConclusionHYDROGEN BONDING-MEDIATED COOPERATIVE ORGANOCATALYSIS BY MODIFIED CINCHONA ALKALOIDSIntroductionThe Emergence of Highly Enantioselective Base OrganocatalysisHydrogen Bonding-BasedConclusion and OutlooksCOOPERATION OF TRANSITION METALS AND CHIRAL BRØNSTED ACIDS IN ASYMMETRIC CATALYSISGeneral IntroductionCooperative Catalysis of Palladium(II) and a Brønsted AcidCooperative Catalysis of Palladium(0) and a Brønsted AcidCooperative Catalysis of a Rhodium Complex and a Brønsted AcidCooperative Catalysis of a Silver Complex and a Brønsted AcidCooperative Catalysis of a Copper Complex and a Brønsted AcidCooperative Catalysis of an Iridium Complex and a Brønsted AcidCooperative Catalysis of an Iron Complex and a Brønsted AcidPerspectiveCOOPERATIVE CATALYSIS INVOLVING CHIRAL ION PAIR CATALYSTSIntroductionChiral Cation-Based CatalysisChiral Anion Based CatalysisSynopsisBIMETALLIC CATALYSIS: COOPERATION OF CARBOPHILIC METAL CENTERSIntroductionHomobimetallic CatalystsHeterobimetallic CatalystsSynopsisCOOPERATIVE H2 ACTIVATION BY BORANE-DERIVED FRUSTRATED LEWIS PAIRSIntroductionMechanistic ConsiderationsGeneral ConsiderationsHydrogenation of IminesHydrogenation of Enamines and Silylenol EthersHydrogenation of HeterocyclesHydrogenation of Enones, Alkylidene Malonates, and NitroolefinsHydrogenation of Unpolarized Olefins and Polycyclic Aromatic HydrocarbonsSummaryCATALYSIS BY ARTIFICIAL OLIGOPEPTIDESCooperative Catalysis by Short PeptidesCooperative Catalysis by Supramolecular SystemsCooperative Catalysis by NanosystemsConclusionsMETALS AND METAL COMPLEXES IN COOPERATIVE CATALYSIS WITH ENZYMES WITHIN ORGANIC-SYNTHETIC ONE-POT PROCESSESIntroductionMetal-Catalyzed In situ-Preparation of an Enzyme's Reagent (Cofactor) Required for the BiotransformationCombination of a Metal-Catalyzed Racemization of a Substrate with a Stereoselective Biotransformation Toward a Dynamic Kinetic ResolutionCombinations of Metal Catalysis and Biocatalysis Toward "Consecutive" One-Pot Processes without Intermediate IsolationSummary and OutlookCOOPERATIVE CATALYSIS ON SOLID SURFACES VERSUS SOLUBLE MOLECULESIntroductionTuning Cooperativity of Acid-Base Bifunctional Groups by Varying the Distance Between Them in a Soluble-Molecule PlatformAcid-Base Bifunctional Catalysts on Two-Dimensional Surfaces: Organic-Inorganic MaterialsCooperative Catalysis on Surfaces versus Soluble Molecular Platforms for Kinetic Resolution of Racemic EpoxidesDepolymerization of Biomass Polymers via Cooperative Catalysis on SurfacesConclusionsCOOPERATIVE CATALYSIS IN POLYMERIZATION REACTIONSIntroductionCooperative Effects for the Polymerization of Lactide and Other Cyclic EstersPolymerization Reactions of Vinyl Monomers with Frustrated Lewis PairsZinc-Based Cooperative Catalysis of Epoxide/CO2 CopolymerizationCooperative Mechanism of Epoxide/CO2 Copolymerization by Salen-Type ComplexesSummaryIndex

About the author

René Peters is professor for Organic Chemistry at the University of Stuttgart, Germany. He studied chemistry at the RWTH Aachen (Germany) and received his doctoral degree in 2000 under supervision of Prof. Dieter Enders. For his postdoctoral studies he joined the group of Prof. Yoshito Kishi at Harvard University, USA. Afterwards, he worked for three years as a process research chemist at F. Hoffmann-La Roche in Basel, Switzerland. In 2004, he joined the faculty of ETH Zürich as assistant professor and since 2008 he holds his current position. His research efforts are mainly directed towards the development of efficient catalytic asymmetric methodologies, in particular using cooperative catalysis.

Summary

Written by experts in the field, this is a much-needed overview of the rapidly emerging field of cooperative catalysis.

The authors focus on the design and development of novel high-performance catalysts for applications in organic synthesis (particularly asymmetric synthesis), covering a broad range of topics, from the latest progress in Lewis acid / Brønsted base catalysis to e.g. metal-assisted organo catalysis, cooperative metal/enzyme catalysis, and cooperative catalysis in polymerization reactions and on solid surfaces. The chapters are classified according to the type of cooperating activating groups, and describe in detail the different strategies of cooperative activation, highlighting their respective advantages and pitfalls. As a result, readers will learn about the different concepts of cooperative catalysis, their corresponding modes of operation and their applications, thus helping to find a solution to a specific synthetic catalysis problem.

Product details

• Authors: René Peters
• Assisted by: Ren Peters (Editor), René Peters (Editor)
• Publisher: Wiley-VCH
• Languages: English, German
• Product format: Hardback
• Released: 01.03.2015
• EAN: 9783527336890
• ISBN: 978-3-527-33689-0
• No. of pages: 428
• Dimensions: 175 mm x 250 mm x 27 mm
• Weight: 1119 g
• Illustrations: 180 SW-Abb.
• Series: Blackwell Verlag
• Subjects: Natural sciences, medicine, IT, technology > Chemistry; Chemie, Organische Chemie, Katalyse, chemistry, Catalysis, Methods - Synthesis & Techniques, Organische Chemie / Methoden, Synthesen, Verfahren, Sustainable Chemistry & Green Chemistry, Nachhaltige u. Grüne Chemie, Biochemie u. Chemische Biologie, Biochemistry (Chemical Biology), Kooperative Katalyse