Read more
Informationen zum Autor Ryohei Yamaguchi is an Emeritus Professor of Chemistry at Kyoto University, Japan. Previously, he worked as a postdoctoral fellow at University of Minnesota. His research includes the development of selective and catalytic organic reactions by means of metal reagents/complexes directed towards green organic synthesis. Ken-ichi Fujita is an Associate Professor of Chemistry at Kyoto University, Japan. Previously, he worked as a postdoctoral fellow at Yale University, USA and received the Incentive Award in Synthetic Organic Chemistry, Japan in 2006. His research focuses on the development of new catalytic systems for green organic synthesis. Klappentext The selection of ligands is critical to carrying out practical and efficient reactions, and there has been an increasing desire to devise and develop greener alternatives for such chemical transformations. Chemists must consider the importance of ligands in transition metal complexes used as catalysts-- including selectivity and reactivity characteristics and how to choose different ligands in order to perform practical and efficient synthesis. Motivated by such a pressing need, this book serves as a manual for synthetic organic and catalytic chemists - guiding them in the design and choice of ligands to catalyze green organic transformations. Offering a useful resource, the authors present important industrial perspective and provide rational explanations of ligand effects, impacts, and novelty. Divided into four parts, the book covers different ligands and reactions: N-heterocyclic carbene ligands, cyclopentadienone and related functional ligands, pincer ligands, and notable miscellaneous ligands; all in transition metal catalyzed hydrogen transfer and dehydrogenative reactions. Additional features include: - Discussion of ligand selectivity/reactivity characteristics - Up-to-date discussion on hydrogen transfers and related reactions - Emphasis on ligand designs and applications necessary for more practical and efficient syntheses While scattered literature on efficient ligands for transformations exists on the topics, this book compiles the most up-to-date and necessary information emphasizing design and application under one cover Zusammenfassung Serving as a user's manual for synthetic organic and catalytic chemists! this book guides chemists in the design and choice of ligands to catalyze green organic transformations. Offering a useful resource! the authors present important industrial perspective and provide rational explanations of ligand effects! impacts! and novelty. Inhaltsverzeichnis Preface ix Abbreviation xi Part I?-Heterocyclic Carbene Ligands in Transition Metal Catalyzed Hydrogen Transfer and Dehydrogenative Reactions 1 1 Oxidation and Hydrogenation Reactions Catalyzed by Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands 3 1.1 Introduction, 3 1.2 Oxidation of Alcohols Based on Hydrogen Transfer, 3 1.3 Oxidation of Alcohols Based on Dehydrogenation, 10 1.4 Hydrogenation and Transfer Hydrogenation of Carbon-Heteroatom Unsaturated Bonds, 12 1.5 Other Related Hydrogenative Reactions, 21 References, 25 2 Bond-Forming Reactions Catalyzed by Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands 27 2.1 Introduction, 27 2.2 Carbon-Carbon Bond Formation Based on Hydrogen Transfer, 27 2.3 Carbon-Nitrogen Bond Formation Based on Hydrogen Transfer and Dehydrogenation, 37 2.4 Carbon-Oxygen Bond Formation Based on Hydrogen Transfer and Dehydrogenation, 46 References, 52 Part ii ?Cyclopentadienone/?Hydroxycyclopentadienyl and Related Ligands in Transition Metal Catalyzed Hydrogen Transfer and Dehydrogenative Reactions 55 3 Oxidation and Hydrogenati...
