Unimolecular Reaction Dynamics - Theory and Experiments

Klappentext The field of unimolecular reaction has witnessed impressive advances in both experimental and theoretical techniques during the past 20 years. These developments have resulted in experimental measurements that finally permit critical test of the major assumptions made more than 60 years ago when Rice and Ramsperger and Kassel first proposed their statistical RRK theory of unimolecular decay. Zusammenfassung A central core of theoretical and experimental physical chemistry is covered by this book, which looks at energy selected reactions. Three major aspects of unimolecular reactions are covered: the preparation of the reactants in selected energy states; the rate of dissipation of the activated molecule; and the partitioning of the excess energy among the final products. Theoretical and analytical chemists working in research laboratories will find the coverage of both theoretical and practical aspects of the topic invaluable for furthering their work. Inhaltsverzeichnis 1.: Introduction 2.: Vibrational/Rotational Energy Levels 3.: Potential Energy Surfaces 4.: State Preparation and Intramolecular Vibrational Energy Redistribution 5.: Experimental Methods in Unimolecular Dissociation Studies 6.7.: Theory of Unimolecular Decomposition - The Statistical ApproachApplications and Extensions of Statistical Theories 8.: Dynamical Approaches 9.: Product Energy Distributions 10.: The Dissociation fo Small and Large Clusters Appendix

Product details

• Authors: T. Hase Baer, Tomas Baer, Tomas (Professor of Chemistry Baer, Tomas Hase Baer, Baer Tomas, William L. Hase, William L. (Professor of Chemistry Hase, Hase William L.
• Publisher: Oxford University Press
• Languages: English
• Product format: Hardback
• Released: 08.08.1996
• EAN: 9780195074949
• ISBN: 978-0-19-507494-9
• No. of pages: 448
• Series: International Series of Monographs on Chemistry; International Series of Monogr; International Series of Monographs on Chemistry; International Monographs on Ch
• Subjects: Natural sciences, medicine, IT, technology > Chemistry > Physical chemistry; SCIENCE / Chemistry / Analytic, SCIENCE / Chemistry / Physical & Theoretical, Physical Chemistry, Spectrum analysis, spectrochemistry, mass spectrometry