Read more
Zusatztext Written by the chemist originators as well as by a theorist who has been one of the protagonists of the development of the field, this book is explicitly addressed to an audience of chemists and physicists and aims to use a language suitable for the two communities. Informationen zum Autor Dante GatteschiDepartment of Chemistry Università degli Studi di Firenzevia della Lastruccia 350019 Sesto FiorentinoITALY; Roberta SessoliDepartment of Chemistry Università degli Studi di Firenzevia della Lastruccia 350019 Sesto FiorentinoITALY; Jacques Villain17 Boulevard de Jomardière,F-38120 Saint-Egrève Klappentext Nanomagnetism is a rapidly expanding area of research which appears to be able to provide novel applications. Magnetic molecules are at the very bottom of the possible size of nanomagnets and they provide a unique opportunity to observe the coexistence of classical and quantum properties.The discovery in the early 90's that a cluster comprising twelve manganese ions shows hyteresis of molecular origin, and later proved evidence of quantum effects, opened a new research area which is still flourishing through the collaboration of chemists and physicists. This book is the firstattempt to cover in detail the new area of molecular nanomagnetism, for which no other book is available. In fact, research and review articles and book chapters are the only tools available for new comers and the experts in the field. It is written by the chemists originators and by a theoristwho has been one of the protagonists of the development of the field, and is explicitly addressed to an audience of chemists and physicists, aiming to use a language suitable for the two communities. Zusammenfassung Focuses on molecular nanomagnetism, a research area which is of interest to chemists and physicists who want to discover the beauty of the molecular world and its potentialities to give various classes of magnetic materials. Inhaltsverzeichnis 1: Introduction 2: Magnetic Interactions in Molecular Systems 3: Observation of Microscopic Magnetism 4: Single Molecular Magnets 5: Thermally Activated Magnetic Relaxation 6: Magnetic Tunnelling of an Isolated Spin 7: Introduction to Path Integrals 8: Tunnelling in a Time-Dependent Magnetic Field at Low Temperature 9: Interaction of a Spin with the External World at Low Temperature 10: Tunnelling between Excited States 11: Coherence and Decoherence 12: Disorder and Magnetic Tunnelling 13: More Experiments on Single Molecule Magnets 14: Other Magnetic Molecules 15: Emerging Trends in Molecular Nanomagnetism A: Systems of Units, Physical Contants and Basic Mathematical Tools B: The Magnetic Field C: How Irreversibility Comes In D: Basic Properties of the Master Equation E: Derivation of the Arrhenius Law F: Phonons and How to Use Them G: High Order Perturbation Theory H: Proof of the Landau-Zener-Stuckelberg Formula I: Tunnelling Between Hyperfine States J: Specific Heat K: master Equation for the Density Matrix ...