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This volume focuses on the environmental factors that govern the processes that determine the fate of organic chemicals in natural and engineered systems. This understanding is then applied to quantitatively assess the environmental behaviour of organic chemicals.
List of contents
Preface.
Part I: Introduction.
1. General Topic and Overview.
2. An Introduction to Environmental Organic Chemicals.
Part II: Equilibrium Partitioning Between Gaseous, Liquid, and Solid Phases.
3. Partitioning: Molecular Interactions and Thermodynamics.
4. Vapor Pressure.
5. Activity Coefficient and Solubility in Water.
6. Air-Organic Solvent and Air-Water Partitioning.
7. Organic Liquid-Water Partitioning.
8. Organic Acids and Bases: Acidity Constant and Partitioning Behavior.
9. Sorption I: General Introduction and Sorption Processes Involving Organic Matter.
10. Sorption II: Partitioning to Living Media - Bioaccumulation and Baseline Toxicity.
11. Sorption III: Sorption Processes Involving Inorganic Surfaces.
Part III: Transformation Processes.
12. Thermodynamics and Kinetics of Transformation Reactions.
13. Chemical Transformations I: Hydrolysis and Reactions Involving Other Nucleophilic Species.
14. Chemical Transformations II: Redox Reactions.
15. Direct Photolysis.
16. Indirect Photolysis: Reactions with Photooxidants in Natural Waters and in the Atmosphere.
17. Biological Transformations.
Part IV: Modeling Tools: Transport and Reaction.
18. Transport by Random Motion.
19. Transport Through Boundaries.
20. Air-Water Exchange.
21. Box Models.
22. Models in Space and Time.
Part V: Environmental Systems and Case Studies.
23. Ponds, Lakes, and Oceans.
24. Rivers.
25. Groundwater.
Appendix.
Bibliography.
Index (Subject Index, Compound Index, List of Illustrative Examples).
Report
"...a comprehensive set of fundamental concepts that provides the quantitative tools necessary to evaluate the fate of the organic chemicals in the environment..." ( Vadose Zone Journal , May 2007)
"...can be considered as the Bible of Organic Environmental Chemistry .... will help to establish the subject discipline in the future" ( International Journal of Environmental Analytical Chemistry , 2004)