Fr. 134.00

Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C-H Bond Activation

English · Hardback

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Description

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Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.

List of contents

General Introduction.- Iron-Catalyzed Naphthalene Synthesis from Alkyne and Grignard Reagent.- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Grignard Reagent.- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Aryl Bromide Mediated by Metallic Magnesium.- Summary and Perspectives.

Summary

Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.

Product details

Authors Arimasa Matsumoto
Publisher Springer, Berlin
 
Languages English
Product format Hardback
Released 07.02.2014
 
EAN 9784431549277
ISBN 978-4-431-54927-7
No. of pages 74
Dimensions 166 mm x 10 mm x 241 mm
Weight 250 g
Illustrations XIII, 74 p. 105 illus.
Series Springer Theses
Springer Theses
Subject Natural sciences, medicine, IT, technology > Chemistry > Organic chemistry

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