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Klappentext This volume aims to provide a firm grounding in the principles and techniques employed in electronic and photoelectron spectroscopy. Zusammenfassung Electronic and photoelectron spectroscopy can provide extraordinarily detailed information on the properties of molecules. This book aims to provide the reader with a firm grounding of the basic principles and experimental techniques employed! through the extensive use of case studies. Inhaltsverzeichnis Preface; List of journal abbreviations; Part I. Foundations of Electronic and Photoelectron Spectroscopy: 1 Introduction; 2. Electronic structure; 3. Angular momentum in spectroscopy; 4. Classification of electronic states; 5. Molecular vibrations; 6. Molecular rotations; 7. Transition probabilities; Part II. Experimental Techniques: 8. The sample; 9. Broadening of spectroscopic lines; 10. Lasers; 11. Optical spectroscopy; 12. Photoelectron spectroscopy; Part III. Case Studies: 13. Ultraviolet photoelectron spectrum of CO; 14. Photoelectron spectra of CO2, OCS, and CS2 in a molecular beam; 15. Photoelectron spectrum of NO2¿; 16. Laser-induced fluorescence spectroscopy of C3: rotational structure in the 300 nm system; 17. Photoionization spectrum of diphenylamine: an unusual illustration of the Franck-Condon principle; 18. Vibrational structure in the electronic spectrum of 1,4-benzodioxan: assignment of low frequency modes; 19. Vibrationally resolved ultraviolet spectroscopy of propynal; 20. Rotationally resolved laser excitation spectrum of propynal; 21. ZEKE spectroscopy of Al(H2O) and Al(D2O); 22. Rotationally resolved electronic spectroscopy of the NO free radical; 23. Vibrationally resolved spectroscopy of Mg+-rare gas complexes; 24. Rotationally resolved spectroscopy of Mg+-rare gas complexes; 25. Vibronic coupling in benzene; 26. REMPI spectroscopy of chlorobenzene; 27. Spectroscopy of the chlorobenzene cation; 28. Cavity ringdown spectroscopy of the a1¿¿X3¿g¿ transition in O2; Appendices; Index....
