Ligand-Field Parameters

Klappentext This volume was originally published in 1973! it is concerned with the nature of the ligand-field parameters used to describe the electronic properties of transition metal complexes having cubic and lower symmetries. Zusammenfassung This volume was originally published in 1973. The nature of the non-symmetry determined aspects of ligand-field theory receives inadequate treatment in most texts. This book is concerned with the nature of the ligand-field parameters used to describe the electronic properties of transition metal complexes having cubic and lower symmetries. Inhaltsverzeichnis 1. Symmetry versus splitting parameters; 2. The crystal-field formalism; 3. Interelectron repulsion parameters; 4. Radical parameters for angularly-distorted systems; 5. Radical parametres for quadrate symmetry; 6. The nature and calculation of 10Dq; 7. A crystal-field approach to radical parameters; 8. Semi-empirical molecular-orbital approaches; 9. The Nephelauxetic effect.

Product details

• Authors: M. Gerloch, M. Slade Gerloch, Gerloch M., R. C. Slade
• Publisher: Cambridge University Press ELT
• Languages: English
• Product format: Paperback / Softback
• Released: 19.03.2009
• EAN: 9780521105668
• ISBN: 978-0-521-10566-8
• No. of pages: 248
• Subjects: Natural sciences, medicine, IT, technology > Chemistry > Physical chemistry; SCIENCE / Chemistry / Physical & Theoretical, Physical Chemistry