Olefin Metathesis and Metathesis Polymerization

Informationen zum Autor K.J. Ivin obtained his Ph.D. in 1948 from the University of Cambridge, England, and then held fellowships at NRC, Ottawa, Canada and the University of Leeds, England. He was appointed to the academic staff at Leeds in 1953 and moved to The Queen's University of Belfast in 1966 as Professor of Physical Chemistry. Since retiring in 1986 he has maintained an active collaboration with various groups working on ring-opening metathesis polymerization. J.C. Mol graduated as a chemical engineer from the Technical University of Delft, The Netherlands, in 1964. He obtained his Ph.D. in chemistry from the University of Amsterdam in 1971 where he presently heads a research group working on heterogeneous catalysis, particularly in the field of olefin metathesis. Klappentext Olefin Metathesis by K. J. Ivin was published in 1983. Olefin Metathesis and Metathesis Polymerization provides a broad, up-to-date account of the subject from its beginnings around 1960 to the latest applications in organic synthesis. It is assembled along the same lines as the earlier book so as to be useful to both teachers and researchers and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis, materials science and chemical engineering. "Coverage of the literature is up-to-date...,and the book is very well indexed; there is no difficulty in finding your way to a topic of interest. As a document of an important branch of organometallic chemistry, this book is complete and should satisfy all chemists with an interest in olefin metathesis and related reactions." --Warren E. Piers, University of Calgary, JOURNAL OF AMERICAN CHEMISTRY SOCIETY "Any reader wishing to know anything about olefin matathesis and metathesis polymerization cannot do better than start with this excellant monograph... Nobody active in the area can afford to be without this monograph and any library which serves a research community interest in catalysis, organic synthesis and polymer science and technology will need this book on its shelves." --W.J. Feast, POLYMER INTERNATIONAL, Vol. 45, No. 3, March 1998 Zusammenfassung Provides an account of olefin metathesis from its beginnings in 1957 to the modern applications in organic synthesis. This book discusses different classes of olefin metathesis and the choice of reaction conditions and catalyst; and considers commercial processes with examples from various technologies. Inhaltsverzeichnis Preface. Abbreviations. Introduction: The Olefin Metathesis Reaction. Brief History. The Metal Carbene Mechanism. Equilibria and Stereoselectivity. Survey of Catalyst Systems: Group IV. Group V. GroupVI. Group VII. Group VIII. Photochemically Activated Catalysts. The Metal Carbene/Metallacyclobutane Mechanism: Evidence from Cross-Metathesis Reactions. Evidence from the Stereochemistry of Metathesis of Internal Olefins. Evidence from Ring-Opening Metathesis Polymerization (ROMP). Evidence from the reactions of Well-Defined Metal Carbene Complexes. Evidence from the Reactions of Metallacyclobutane Complexes. Evidence of Initiating Species in Systems with Non-Carbene Catalysts. Theoretical Treatments. Related Reactions: [2+2] Reactions Between Compounds Containing Multiple Bonds. Relationship to Ziegler-Natta Polymerization. Involvement of Three-Membered Ring Compounds in Metathesis Reactions. Ethene and Terminal Alkenes: Ethene. Propene. But-1-ene and its Derivatives. Pent-1-ene and its Derivatives. Hex-1-ene and its Derivatives. Higher Acyclic Terminal Alkenes. Acyclic Disubstituted and Trisubstituted Ethenes. Cis/trans Isomerization. Pent-2-ene and 4-Substituted Derivatives. Hex-2-ene and 4-Methylhex-2-ene.Hept-2-ene and Hept-3-ene. Higher Acyclic Internal Olefins. Stereoselectivity in the Metathesis of Acyclic Olefins. 1,1-Disubstituted Olefins. Trisu...

List of contents

Preface. Abbreviations. Introduction: The Olefin Metathesis Reaction. Brief History. The Metal Carbene Mechanism. Equilibria and Stereoselectivity. Survey of Catalyst Systems: Group IV. Group V. GroupVI. Group VII. Group VIII. Photochemically Activated Catalysts. The Metal Carbene/Metallacyclobutane Mechanism: Evidence from Cross-Metathesis Reactions. Evidence from the Stereochemistry of Metathesis of Internal Olefins. Evidence from Ring-Opening Metathesis Polymerization (ROMP). Evidence from the reactions of Well-Defined Metal Carbene Complexes. Evidence from the Reactions of Metallacyclobutane Complexes. Evidence of Initiating Species in Systems with Non-Carbene Catalysts. Theoretical Treatments. Related Reactions: [2+2] Reactions Between Compounds Containing Multiple Bonds. Relationship to Ziegler-Natta Polymerization. Involvement of Three-Membered Ring Compounds in Metathesis Reactions. Ethene and Terminal Alkenes: Ethene. Propene. But-1-ene and its Derivatives. Pent-1-ene and its Derivatives. Hex-1-ene and its Derivatives. Higher Acyclic Terminal Alkenes. Acyclic Disubstituted and Trisubstituted Ethenes. Cis/trans Isomerization. Pent-2-ene and 4-Substituted Derivatives. Hex-2-ene and 4-Methylhex-2-ene.Hept-2-ene and Hept-3-ene. Higher Acyclic Internal Olefins. Stereoselectivity in the Metathesis of Acyclic Olefins. 1,1-Disubstituted Olefins. Trisubstituted Ethenes. Acyclic Functionalized Alkenes: Esters. Other Carbonyl-Containing Compounds. Ethers. Amines. Nitriles. Chlorides and Bromides. Sulfides and Sulfonates. Silancs and Germanes. Phospanes. Acyclic Dienes: Double Bonds Linked only by C Atoms. Double Bonds Linked by C and Si, Ge orSn Atoms. Double Bonds Linked by C and N Atoms. Double Bonds Linked by C, Si, and O Atoms. Divinylferrocene. Some Further Applications in Organic Synthesis. Copolymers by Metathesis Condensation. Cross-Metathesis Between Acyclic Compounds: Ethene.Propene. Butenes. Pentenes. Hexenes. Higher Olefins. Functionalized Olefins. Acetylenes: Metathesis Reactions Involving Total Cleavage of the C=C bond. Metathesis Reactions Involving Cleavage of Two of the thress C=C Bonds. Metathesis Reactions of Enynes and Dienynes. Other Metathesis Routes to Polyacetylenes. Ring-Opening Metathesis Polymerization: General Aspects: Thermodynamic Aspects. Efficiency of Initiation. The Use of Chain-Transfer Agents. Molecular Weight Distributions. Polymer Micostructure. Monocyclic Alkenes and Polyenes: Four-Membered Rings. Five-Membered Rings. Six-Membered Rings. Seven-Membered Rings. Eight-Membered Rings. Nine-Membered Rings. Ten-Membered Rings. Twelve-Membered and Other Rings. Polycyclic Alkenes: Monomers Containing a Fused Cyclobutene Ring. Monomers Containing a Fused Cyclopentene Ring and One Double Bond. Monomers Containing a Fused Cyclopentene Ring and More than One Double Bond. Bicyclo[2.2.1] Compounds Containing Heteroatoms in the Ring System. Other Bicyclic Compounds. Copolymers of Cycloalkenes: Direct Metathesis Copolymerization. Cyclic Co-Oligomers. Block Copolymers by Sequential Addition of Monomers to Living Systems. Block Copolymers by Modification of Homopolymers. Comb and GraftCopolymers. Copolymers by ROMP in Conjunction with Radical Reactions. Cross-Metathesis Between Cyclic and Acyclic Olefins: End-Groups and Telomers. Dependence of Molecular Weight on [M2]/[M1]. Kinetic Data. Degradation of UnsaturatedPolymers by Metathesis: Degradation by Intramolecular Metathesis. Applications of the Olefin Metathesis Reaction: The Phillips Triolefin Process. The Neohexene Process. The Shell Higher Olefins Process. Other Multistage Processes Involving Metathesis. The Isoamylene Process. (Circle around alpha and omega) ((-Diolefins. trans-Poly(1-Pentenylene). trans-Poly(1-octenylene). Polymers of Norhornene. Polymers of Norbornene Derivatives. Miscellaneous. Bibliogra

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"Coverage of the literature is up-to-date...,and the book is very well indexed; there is no difficulty in finding your way to a topic of interest. As a document of an important branch of organometallic chemistry, this book is complete and should satisfy all chemists with an interest in olefin metathesis and related reactions." --JOURNAL OF AMERICAN CHEMISTRY SOCIETY
"Any reader wishing to know anything about olefin matathesis and metathesis polymerization cannot do better than start with this excellant monograph. . . Nobody active in the area can afford to be without this monograph and any library which serves a research community interest in catalysis, organic synthesis and polymer science and technology will need this book on its shelves." --POLYMER INTERNATIONAL, Vol. 45, 1998

Product details

• Authors: K J Ivin, K. J. Ivin, K.J. Ivin, K.j. Mol Ivin, K. J. Ivin, J C Mol, J. C. Mol, Mol J. C.
• Publisher: ELSEVIER SCIENCE BV
• Languages: English
• Product format: Hardback
• Released: 07.01.1997
• EAN: 9780123770455
• ISBN: 978-0-12-377045-5
• No. of pages: 496
• Subjects: Natural sciences, medicine, IT, technology > Chemistry > Organic chemistry; ORGANIC CHEMISTRY, SCIENCE / Chemistry / Organic, SCIENCE / Chemistry / Physical & Theoretical, Physical Chemistry