Atomic Scale Characterization and First-Principles Studies of Si N Interfaces

This thesis presents results from a combined atomic-resolution Z-contrast and annular bright-field imaging and electron energy loss spectroscopy in the Scanning Transmission Electron Microscopy, as well as first principles studies of the interfaces between crystalline beta-Si₃N₄ and amorphous (i) CeO2-x as well as (ii) SiO2 intergranular film (IGF). These interfaces are of a great fundamental and technological interest because they play an important role in the microstructural evolution and mechanical properties of Si3N4 ceramics used in many high temperature and pressure applications. The main contribution of this work is its detailed description of the bonding characteristics of light atoms, in particular oxygen and nitrogen, at these interfaces, which has not been achieved before. The atomic-scale information on the arrangement of both light and heavy atoms is critical for realistic modeling of interface properties, such as interface strength and ion transport, and will facilitate increased control over the performance of ceramic and semiconductor materials for a wide-range of applications.

List of contents

Silicon Nitride Ceramics.- Theoretical Methods and Approximations.- Overview of Experimental Tools.- Structural Energetics of beta-Si₃N4 (1010) Surfaces.- Atomic Resolution Study of the Interfacial Bonding at SI₃N₄/CEO_2- Grain Boundaries.- Atomic Resolution Study of beta-Si₃N₄/ SIO₂ Interfaces.- Imagine Bulk -SI₃N₄.- Conclusions and Future Work.- Appendices.- Cited Literature.

Summary

This thesis presents results from a combined atomic-resolution Z-contrast and annular bright-field imaging and electron energy loss spectroscopy in the Scanning Transmission Electron Microscopy, as well as first principles studies of the interfaces between crystalline β−Si₃N₄ and amorphous (i) CeO2-x as well as (ii) SiO2 intergranular film (IGF).  These interfaces are of a great fundamental and technological interest because they play an important role in the microstructural evolution and mechanical properties of Si3N4 ceramics used in many high temperature and pressure applications.  The main contribution of this work is its detailed description of the bonding characteristics of light atoms, in particular oxygen and nitrogen, at these interfaces, which has not been achieved before.  The atomic-scale information on the arrangement of both light and heavy atoms is critical for realistic modeling of interface properties, such as interface strength and ion transport, and will facilitate increased control over the performance of ceramic and semiconductor materials for a wide-range of applications.

Product details

• Authors: Weronika Walkosz
• Publisher: Springer, Berlin
• Languages: English
• Product format: Paperback / Softback
• Released: 27.05.2013
• EAN: 9781461428572
• ISBN: 978-1-4614-2857-2
• No. of pages: 110
• Dimensions: 155 mm x 235 mm x 7 mm
• Weight: 201 g
• Illustrations: XIV, 110 p.
• Series: Springer Theses; Springer Theses
• Subjects: Natural sciences, medicine, IT, technology > Technology > Mechanical engineering, production engineering; B, Ceramics, Microscopy, biotechnology, Glass, Chemistry and Materials Science, spectroscopy, Spectroscopy and Microscopy, Ceramics, Glass, Composites, Natural Materials, Nuclear physics, Materials science, Physical Chemistry, Spectrum analysis, spectrochemistry, mass spectrometry, Scientific equipment, experiments & techniques, Atomic structure, Molecular structure, Atomic/Molecular Structure and Spectra, Atomic and Molecular Structure and Properties, Microsystems and MEMS, Structural engineering, Structural Materials, Industrial chemistry & chemical engineering, Microengineering, composite materials, Composites (Materials)