Monopnictogen Ferrocenes as Ligands for Asymmetric Catalysis

Asymmetric catalysis has become a vital tool for modern synthetic chemists. Ferrocenes are widely-used building blocks of stereoselective catalysts; derivatives such as Josiphos rank amongst the most versatile and efficient ligands. In this thesis, a chiral ferrocene was used as a building block for the synthesis of a variety of monopnictogen ferrocenes. After a general introduction, the synthesis of aminoferrocenes is discussed and preparations and applications of novel substance classes, such as bis(ferrocenyl)NacNac and ferrocenyl ureas, are presented. Furthermore, the chiral ferrocenyl backbone was used for the preparation of phosphinoferrocenes and their potential in gold(I)- and ruthenium(II)- catalyzed reactions was assessed.

About the author

Dr. sc. ETH Zurich. Obtained his BSc and MSc degrees at ETH Zurich. After an internship at Solvias AG, Basel, he returned to ETH Zurich to carry out his doctoral work under Prof. Dr. Antonio Togni and recieved his Dr. sc. degree in 2012.

Product details

• Authors: Raphael Aardoom
• Publisher: Südwestdeutscher Verlag für Hochschulschriften
• Languages: English, German
• Product format: Paperback / Softback
• Released: 01.01.2013
• EAN: 9783838136288
• ISBN: 978-3-8381-3628-8
• No. of pages: 220
• Subject: Natural sciences, medicine, IT, technology > Chemistry > Inorganic chemistry