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"Commemorating the 25th edition and the 50th year of the prestigious International Conference on Organometallic Chemistry, Advances in Organometallic Chemistry provides a snapshot of the hottest topics in organometallic chemistry today. This compilation contains contributions from selected, renowned, and invited speakers, addressing the preparation and use of organometallics in cutting-edge application areas. Suitable for students and practitioners, the book outlines the principles and general propertiesof organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications"--
List of contents
PREFACE xi
CONTRIBUTORS xv
PART I ACTIVATION AND FUNCTIONALIZATION OF CARBON SINGLE BONDS AND OF SMALL
MOLECULES 1
1 Organometallic Complexes as Catalysts in Oxidation of C--H Compounds 3
Georgiy B. Shul'pin
2 Toward Functionalization of Alkanes Under Environmentally Benign Conditions 15
Armando J. L. Pombeiro
3 Self-assembled Multicopper Complexes and Coordination Polymers for Oxidation and Hydrocarboxylation of Alkanes 27
Alexander M. Kirillov, Marina V. Kirillova, and Armando J. L. Pombeiro
4 Activation of C--O and C--F Bonds by Pincer-iridium Complexes 39
Jason Hackenberg, Karsten Krogh-Jespersen, and Alan S. Goldman
5 Functionalization of sp2 and sp3 Carbon Centers Catalysed by Polyoxometalates and Metalloporphyrins 59
M´ario M. Q. Sim~oes, Isabel C. M. S. Santos, Maria Gra¸ca P. M. S. Neves, Ana M. V. Cavaleiro, and Jos´e A. S. Cavaleiro
6 Quasi-borinium Cation Based on Cobalt Bis(dicarbollide): Its Lewis Acidity and C--H and C--X Bond Activation 73
V. I. Bregadze, I. B. Sivaev, I. D. Kosenko, I. A. Lobanova, Z. A. Starikova, and I. A. Godovikov
7 Transition-metal-promoted Functionalization of Carboranes 81
Zaozao Qiu and Zuowei Xie
8 Weak Interactions and M--H Bond Activation 97
Elena Shubina, Natalia Belkova, Oleg Filippov, and Lina Epstein
PART II ORGANOMETALLIC SYNTHESIS AND CATALYSIS 111
9 Complexes with Protic N-Heterocyclic Carbene (NR,NH-NHC) Ligands 113
F. Ekkehardt Hahn
10 Cyclopentadienyl-functionalized N-Heterocyclic Carbene Complexes of Iron and Nickel: Catalysts for Reductions 133
Beatriz Royo
11 Palladium-(acyclic diaminocarbene) Species as Alternative to Palladium-(nitrogen heterocyclic carbenes) in Cross-coupling Catalysis 145
Vadim P. Boyarskiy, Konstantin V. Luzyanin, and Vadim Yu. Kukushkin
12 Synthesis of Metallocenes Via Metathesis in Metal Coordination Spheres 157
Antoni Pietrzykowski and W(c)(c)odzimierz Buchowicz
13 Metal-mediated [2 + 3] Dipolar Cycloaddition to Substrates with CN Triple Bond: Recent Advances 171
Konstantin V. Luzyanin and Maxim L. Kznetsov
14 Coordination Chemistry of Oxazoline/Thiazoline-based P,N Ligands 185
Shuanming Zhang, Roberto Pattacini, and Pierre Braunstein
15 "Click" Copper Catalyzed Azide-alkyne Cycloaddition (CuAAC) in Aqueous Medium 199
Joaqu´(c)¥n Garc´(c)¥a-A´lvarez and Jose´ Gimeno
16 Organogold Catalysis: Homogeneous Gold-catalyzed Transformations for a Golden Jubilee 207
Fabien Gagosz
17 Vanadium(IV) Complexes Derived from Aromatic o-Hydroxyaldehydes and Tyrosine Derivatives: Catalytic Evaluation in Sulfoxidations 227
Jo~ao Costa Pessoa, Isabel Correia, and Pedro Ad~ao
18 Microwave-assisted Catalytic Oxidation of Alcohols to Carbonyl Compounds 233
Yauhen Yu. Karabach, Maximilian N. Kopylovich, Kamran T. Mahmudov, and Armando J. L. Pombeiro
19 Oxidation of Glycerol with Hydrogen Peroxide Catalyzed by Metal Complexes 247
Dalmo Mandelli, Wagner A. Carvalho, Lidia S. Shul'pina, Alexander M. Kirillov, Marina V. Kirillova,
Armando J. L. Pombeiro, and Georgiy B. Shul'pin
20 Involvement of an Acetato Ligand in the Reductive Elimination Step of the Rhodium-catalyzed Methanol Carbonylation 259
Duc Hanh Nguyen, Nicolas Lassauque, Thomas Davin, Laurent Maron, Carole Le Berre, Philippe Serp, and Philippe Kalck
21 Half-sandwich Rhodium(III), Iridium(III), and Ruthenium(II) Complexes with Ancillary Pyrazole-based Ligands 269
Claudio Pettinari, Riccardo Pettinari, Corrado Di Nicola, and Fabio Marchetti
22 Carbon-scorpionate Complexes in Oxidation Catalysis 285
Lu´(c)¥sa M. D. R. S. Martins and Armando J. L. Pombeiro
23 Toward Chemoselective Bioconjugative Desulfitative Cat
Report
"The book is written in good scientific English and should be easily understood by a graduate-level scientist who has some familiarity with the topics." ( Applied Organometallic Chemistry , 1 May 2015)
