Fr. 916.00

Grignard Reagents - New Developments

Hardback

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Zusatztext "...this book fills a need....it should be in every university and industrial library."--Angewandte Chemie! 18th September 2000 Klappentext Publishing 100 years after Grignard proposed his simple procedure for preparing solutions of organomagnesium compounds! leading experts present authoritative perspectives on the current status of 12 areas that have developed significantly in recent years. Contents include:* New Reactions of Grignard Reagents* Stereoselective Reactions of Organomagnesium Compounds* Mechanistic Features of Organomagnesium Compounds* Industrial Applications and Strategy* Unusual Organomagnesium Compounds* Structures of Organomagnesium Solids and SolutionsAt the close of its first century! these chapters demonstrate the significant developments that are still taking place using Grignard Reagents and related organomagnesium compounds. Grignard Reagents: New Developments will prove of great interest to academic and industrial chemists active in organometallic chemistry of main group metals! organic syntheses! reaction mechanisms and structural organic chemistry. Zusammenfassung Discovered early this century, Grignard reagents remain the most widely--used organometallic compounds. Recent years have seen a steady stream of developments in such areas as the nature of the reagents, the mechanisms by which they react, useful reaction chemistry, and even new types of Grignard reagents. Inhaltsverzeichnis New Reactions of Grignard Reagents.Stereoselective Reactions of Organomagnesium Compounds.Mechanistic Features of Organomagnesium Compounds.Industrial Applications and Strategy.Unusual Organomagnesium Compounds.Structures of Organomagnesium Solids and Solutions.

List of contents

New Reactions of Grignard Reagents.
 
Stereoselective Reactions of Organomagnesium Compounds.
 
Mechanistic Features of Organomagnesium Compounds.
 
Industrial Applications and Strategy.
 
Unusual Organomagnesium Compounds.
 
Structures of Organomagnesium Solids and Solutions.

Report

"Aimed at a broad spectrum of both academic and industrial readers, this excellent and well presented collection of reviews provides a wealth of new insights into an old topic", Christopher Glidewell, , Chemistry and Industry#"Grignard Reagents - Industrial Applications and Strategy is a superb review by F.R. Busch and D.M. de Antonis of the practices used at Pfizer to safely scale-up Grignard Reactions. It includes such topics as reactor configuration, choice of solvent, process hazards, heating and cooling fluids, reaction initiation as well as some industrial examples. The book is worth reading for this chapter alone.", Dr Trevor Laird, , Organic Process Research and Development#

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