Carbon Nanotube-Polymer Composites - Manufacture, Properties, and Applications

Informationen zum Autor BRIAN P. GRADY, PHD, is the holder of the Conoco Du Pont Professorship in the School of Chemical, Biological and Materials Engineering at the University of Oklahoma, as well as the Director of the Institute for Applied Surfactant Research. Dr. Grady has been extremely active in the Society of Plastics Engineers including serving as chair of the Engineering Properties and Structure Division and later as secretary of the Society, and is currently a member of the Executive Committee of the Society of Plastics Engineers. Klappentext The accessible compendium of polymers in carbon nanotubes (CNTs) Carbon nanotubes (CNTs)?extremely thin tubes only a few nanometers in diameter but able to attain lengths thousands of times greater?are prime candidates for use in the development of polymer composite materials. Bringing together thousands of disparate research works, Carbon Nanotube-Polymer Composites: Manufacture, Properties, and Applications covers CNT-polymers from synthesis to potential applications, presenting the basic science and engineering of this dynamic and complex area in an accessible, readable way. Designed to be of use to polymer scientists, engineers, chemists, physicists, and materials scientists, the book covers carbon nanotube fundamentals to help polymer experts understand CNTs, and polymer physics to help those in the CNT field, making it an invaluable resource for anyone working with CNT-polymer composites. Detailed chapters describe the mechanical, rheological, electrical, and thermal properties of carbon nanotube-polymer composites. Including a glossary that defines key terms, Carbon Nanotube-Polymer Composites is essential reading for anyone looking to gain a fundamental understanding of CNTs and polymers, as well as potential and current applications, including electronics (shielding and transparent electrodes), flame retardants, and electromechanics (sensors and actuators), and their challenges. Zusammenfassung Providing a much-needed and thorough overview of polymers in the carbon nanotubes (CNTs), Carbon Nanotube-Polymer Composites provides a fundamental understanding of achievements in the field and highlights key studies that have had significant impact. Inhaltsverzeichnis PREFACE ix CHAPTER 1 INTRODUCTION 1 1.1 Similarities Between Polymers and Nanotubes 1 1.2 Organization of the Book 3 1.3 Why Write This Book? 7 References 9 CHAPTER 2 CARBON NANOTUBES 11 2.1 Overview 11 2.2 Synthesis 16 2.2.1 Arc Discharge 19 2.2.2 Visible Light Vaporization 21 2.2.3 Chemical Vapor Deposition 22 2.3 Purification 25 2.4 Properties 26 2.4.1 Mechanical Properties 27 2.4.2 Electronic, Magnetic, and Thermal Properties 29 2.4.3 Optical Properties 32 2.5 Chemistry 36 2.5.1 Characterizing the Nature of Functionalization 38 2.5.2 Common Functionalization Chemistries 40 2.5.3 Polymer Covalently Bonded to Nanotubes: "Grafting From" 42 2.5.4 Polymer Covalently Bonded to Nanotubes: "Grafting To" 44 2.6 Challenges 44 References 45 CHAPTER 3 DISPERSION, ORIENTATION, AND LENGTHS OF CARBON NANOTUBES IN POLYMERS 59 3.1 Overview 59 3.2 Dispersion Characterization 66 3.2.1 Microscopy 67 3.2.2 Spectroscopy 72 3.3 Methods to Disperse Nanotubes into Low-Viscosity Liquids, Including Monomers 77 3.3.1 Mixing Protocols: Sonication and High-Shear Mixing 79 3.3.2 Dispersions of Nanotubes in Water 81 3.3.3 Dispersions of Nanotubes in Other Solvents 86 3.4 Polymer-Nanotube Dispersions: Solution Methods 88 3.4.1 Dispersion-Reaction 88 3.4.2 Dissolution-Dispersion-Precipitation 90 3.4.3 Dispersion-Dispersion-Evaporation 93 3.5 Polymer-Nanotube Dispersions: Melt Mixing 94 3.6 Polymer-Nanotube Disp...

List of contents

PREFACE ix
 
CHAPTER 1 INTRODUCTION 1
 
1.1 Similarities Between Polymers and Nanotubes 1
 
1.2 Organization of the Book 3
 
1.3 Why Write This Book? 7
 
References 9
 
CHAPTER 2 CARBON NANOTUBES 11
 
2.1 Overview 11
 
2.2 Synthesis 16
 
2.2.1 Arc Discharge 19
 
2.2.2 Visible Light Vaporization 21
 
2.2.3 Chemical Vapor Deposition 22
 
2.3 Purification 25
 
2.4 Properties 26
 
2.4.1 Mechanical Properties 27
 
2.4.2 Electronic, Magnetic, and Thermal Properties 29
 
2.4.3 Optical Properties 32
 
2.5 Chemistry 36
 
2.5.1 Characterizing the Nature of Functionalization 38
 
2.5.2 Common Functionalization Chemistries 40
 
2.5.3 Polymer Covalently Bonded to Nanotubes: "Grafting From" 42
 
2.5.4 Polymer Covalently Bonded to Nanotubes: "Grafting To" 44
 
2.6 Challenges 44
 
References 45
 
CHAPTER 3 DISPERSION, ORIENTATION, AND LENGTHS OF CARBON NANOTUBES IN POLYMERS 59
 
3.1 Overview 59
 
3.2 Dispersion Characterization 66
 
3.2.1 Microscopy 67
 
3.2.2 Spectroscopy 72
 
3.3 Methods to Disperse Nanotubes into Low-Viscosity Liquids, Including Monomers 77
 
3.3.1 Mixing Protocols: Sonication and High-Shear Mixing 79
 
3.3.2 Dispersions of Nanotubes in Water 81
 
3.3.3 Dispersions of Nanotubes in Other Solvents 86
 
3.4 Polymer-Nanotube Dispersions: Solution Methods 88
 
3.4.1 Dispersion-Reaction 88
 
3.4.2 Dissolution-Dispersion-Precipitation 90
 
3.4.3 Dispersion-Dispersion-Evaporation 93
 
3.5 Polymer-Nanotube Dispersions: Melt Mixing 94
 
3.6 Polymer-Nanotube Dispersions: No Fluid Mixing 96
 
3.7 Polymer-Nanotube Dispersions: Impregnation/Infusion 97
 
3.7.1 Nanotube Fiber-Polymer Composites 97
 
3.7.2 Nanotube Sheet-Polymer Composites 99
 
3.7.3 Nanotube Forests-Polymer Composites 101
 
3.7.4 Nanotubes on Already Existing Fibers 101
 
3.8 Challenges 102
 
References 103
 
CHAPTER 4 EFFECTS OF CARBON NANOTUBES ON POLYMER PHYSICS 119
 
4.1 Overview 119
 
4.2 Amorphous Polymers 122
 
4.2.1 Statics: Adsorption and Chain Configuration 122
 
4.2.2 Dynamics: Glass Transition and Diffusion Coefficient 129
 
4.3 Semicrystalline Polymers 142
 
4.3.1 Statics: Unit Cells, Lamellae, Spherulites, and Shish-Kebabs 147
 
4.3.2 Rate Effects: Glass Transition, Crystal Nucleation, and Growth 169
 
4.4 Blends and Block Copolymers 174
 
4.5 Challenges 176
 
References 177
 
CHAPTER 5 MECHANICAL AND RHEOLOGICAL PROPERTIES 191
 
5.1 Overview 191
 
5.2 Rheological Properties (Measurement of Melt and Solution Properties) 200
 
5.2.1 Nonoscillatory Measurements 204
 
5.2.2 Oscillatory Measurements and the Percolation Threshold 208
 
5.3 Mechanical Properties (Measurement of Solid Properties) 212
 
5.3.1 Interfacial Shear Strength 214
 
5.3.2 Tensile, Compressive, and Bending Properties 216
 
5.3.3 Fracture Toughness and Crack Propagation 228
 
5.3.4 Impact Energy 230
 
5.3.5 Oscillatory Measurements 230
 
5.3.6 Other Mechanical Properties 232
 
5.4 Challenges 232
 
References 233
 
CHAPTER 6 ELECTRICAL PROPERTIES 249
 
6.1 Overview 249
 
6.2 Mixed Composites 252
 
6.2.1 Maximum or Plateau Conductivity 260
 
6.2.2 Broadness of Percolation Region (Critical Exponent) 264
 
6.2.3 Percolation Threshold 264
 
6.2.4 Dielectric Constant

Product details

• Authors: BP Grady, Brian P Grady, Brian P. Grady, GRADY BRIAN P, Grady Brian P.
• Publisher: Wiley, John and Sons Ltd
• Languages: English
• Product format: Hardback
• Released: 26.08.2011
• EAN: 9780470596418
• ISBN: 978-0-470-59641-8
• No. of pages: 352
• Subjects: Natural sciences, medicine, IT, technology > Chemistry > Organic chemistry; Nanotechnologie, Polymere, polymer processing, Chemical Engineering, chemische Verfahrenstechnik, Nanotechnology, Allg. Chemische Verfahrenstechnik, Polymer Science & Technology, Polymerwissenschaft u. -technologie, Nanomaterialien, Nanomaterials, Polymerverarbeitung, Kohlenstoffnanomaterialien