Ulteriori informazioni
With its impressive features, gold has led to completely new reaction types in recent years, which in turn have strongly influenced bothorganic catalysis and material science. Other fields where a significant amount of new results has been obtained include nanotechnology,self assembly/supramolecular systems and biochemical/medicinal chemistry. As a result, gold is one of the hottest topics in catalysis atthe moment, with an increasing amount of research being carried out in this field.While focusing on homogeneous catalysis, this monograph also covers the main applications in heterogeneous catalysis. Followinga look at the gold-catalyzed addition of heteroatom nucleophiles to alkynes, it goes on to discuss gold-catalyzed additions to allenes andalkenes, gold-catalyzed benzannulations, cycloisomerization and rearrangement reactions, as well as oxidation and reduction reactions.The whole is finished off with a section on gold-catalyzed aldol and related reactions and the application of gold-catalyzed reactions to naturalproduct synthesis.Of interest to synthetic chemists and inorganic chemists, as well as organic chemists working in homogeneous catalysis, physical andtechnical chemists.
Info autore
A. St. K. Hashmi is Professor for Organic Chemistry at Stuttgart University. Born in Munich, Germany, he completed his studies at the LMU Munich, gaining his doctorate under the supervision of Günter Szeimies. During his post-doctorate at Stanford University, he worked with Barry M. Trost. His further postdoctoral work at the FU Berlin, Vienna University and Frankfurt University with Johann Mulzer and further activities at the University of Tasmania and Marburg University culminated in his position at Stuttgart University in 2001.
Riassunto
With its impressive features, gold has led to completely new reaction types in recent years, which in turn have strongly influenced both
organic catalysis and material science. Other fields where a significant amount of new results has been obtained include nanotechnology,
self assembly/supramolecular systems and biochemical/medicinal chemistry. As a result, gold is one of the hottest topics in catalysis at
the moment, with an increasing amount of research being carried out in this field.
While focusing on homogeneous catalysis, this monograph also covers the main applications in heterogeneous catalysis. Following
a look at the gold-catalyzed addition of heteroatom nucleophiles to alkynes, it goes on to discuss gold-catalyzed additions to allenes and
alkenes, gold-catalyzed benzannulations, cycloisomerization and rearrangement reactions, as well as oxidation and reduction reactions.
The whole is finished off with a section on gold-catalyzed aldol and related reactions and the application of gold-catalyzed reactions to natural
product synthesis.
Of interest to synthetic chemists and inorganic chemists, as well as organic chemists working in homogeneous catalysis, physical and
technical chemists.
Relazione
"In conclusion, this well-written book is recommended to both synthetic chemists and those involved in the study of catalysis." ( Organic Process Research & Development , 1 May 2013)